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个人信息Personal Information
副教授
博士生导师
硕士生导师
性别：女
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：高分子材料. 高分子化学与物理
办公地点：化工实验楼a段308
联系方式：hanli@dlut.edu.cn
电子邮箱：hanli@dlut.edu.cn
The terpolymerization of ethylene and propylene with isoprene via THF-containing half-sandwich scandium catalysts: a new kind of ethylene-propylene-diene rubber and its functionalization
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论文类型：期刊论文
发表时间：2017-08-28
发表刊物：POLYMER CHEMISTRY
收录刊物：Scopus、SCIE、EI
卷号：8
期号：32
页面范围：4651-4658
ISSN号：1759-9954
摘要：The terpolymerization of ethylene and propylene with isoprene was performed catalyzed by half-sandwich scandium complexes (C5Me4SiMe3)Sc(CH2SiMe3)(2)(THF) (1) and [1,3-(Me2Si)(2)C9H5]Sc(CH2SiMe3)(2) (THF) (2) in combination with 1 equiv. of [Ph3C][B(C6F5)(4)]. The terpolymers with ethylene contents of 60-84 mol% and isoprene contents of 5-26 mol% (1,4/3,4 approximate to 50/50) were obtained in the presence of complex 1. In comparison, the terpolymers with ethylene contents of 38-75 mol% and isoprene contents of 4-43 mol% (1,4/3,4 approximate to 70/30) were obtained in the presence of complex 2. Subsequently, a functionalized ethylene-propylene-isoprene terpolymer was prepared by the epoxidation of the 1,4-isoprene units in the terpolymer backbone and further hydroxylation/chlorination through ring-opening reaction of the epoxy groups.