- Direct glycerol fuel cell with polytetrafluoroethylene (PTFE) thin film separator
- 点击次数：
- 论文类型： 期刊论文
- 发表时间： 2017-05-01
- 发表刊物： RENEWABLE ENERGY
- 收录刊物： SCIE
- 卷号： 105
- 页面范围： 647-655
- ISSN号： 0960-1481
- 关键字： Direct glycerol fuel cell; Polytetrafluoroethylene (PTFE); Thin films; Porous separator; Anion exchange membrane; Biomass renewables
- 摘要： Anion-exchange membrane-based direct glycerol fuel cells (AEM-DGFCs) can yield high power density, however challenges exist in developing chemically stable AEM5. Here, we demonstrate a porous PTFE thin film, a well-known chemical, electro-chemical, and thermal robust material that can serve as a separator between anode and cathode, thus achieving high DGFC's performance. A simple aqueous phase reduction method was used to prepare carbon nanotube supported PdAg nanoparticles (PdAg/CNT) with an average particle size of 2.9 nm. A DGFC using a PTFE thin film without any further modification with PdAg/CNT anode catalyst exhibits a peak power density of 214.7 mW cm(-2) at 80 degrees C, about 22.6% lower than a DGFC using a state-of-the-art AEM. We report a 5.8% decrease and 11.1% decrease in cell voltage for a PTFE thin film and AEM; similarly, the cell voltage degradation rate decreases from 1.2 to 0.8 mV h(-1) for PTFE thin film, while for AEM, it decreases from 9.6 to 3.0 mV h(-1) over an 80 h durability test period. Transmission electron microscopy results indicate that the average particle size of PdAgICNT increases from 2.9 to 3.7 nm after 80 h discharge; this suggests that PdAg particle growth may be the main reason for the performance drop. (C) 2017 Elsevier Ltd. All rights reserved.
