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论文类型：期刊论文

发表时间：2017-03-09

发表刊物：JOURNAL OF PHYSICAL CHEMISTRY C

收录刊物：SCIE、EI

卷号：121

期号：9

页面范围：5225-5231

ISSN号：1932-7447

摘要：Plasmon-driven diazo coupling reaction of p-nitroaniline (PNA), containing both an amine group (-NH2) and a nitro group (-NO2), in ambient atmosphere environments remains unknown in experiments, on both metal nanoparticles and graphene-mediated metal nanostructures. Using the surface-enhanced Raman scattering (SERS) technique, we presented the surface coupling reactions of PNA under atmospheric environment, adsorbed on the Ag nanoparticle (AgNP) arrays, graphene-coated Ag nanoparticle (G/AgNPs) hybrids, and graphene-covered Ag nanowire (G/ AgNW) composites, respectively. It was found that PNAs were converted into 4,4'-diaminoazobenzene (DAAB) through a selective reduction reaction, rather than oxidized into 4,4'dinitroazobenzene (DNAB). These results may be useful for understanding the reaction mechanism for plasmon-driven chemical reactions of the molecules containing.both amine groups and nitro groups under ambient conditions.