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论文类型：期刊论文

发表时间：2019-10-01

发表刊物：POLYMERS

收录刊物：PubMed、EI、SCIE

卷号：11

期号：10

关键字：miktoarm star copolymer; isotactic-polypropylene; atactic-polystyrene; aggregation morphology

摘要：In this work, a series of isotactic-polypropylene/atactic-polystyrene (iPP/aPS) miktoarm star copolymers, PxSy, was synthesized via an arm-first approach. Varied star macromolecule architectures were fabricated by designing the arm length and the arm numbers (x and y). These miktoarm stars were able to form micelles in selective solvent (N,N '-dimethylformamide (DMF)), in which the insoluble iPP arms formed the core and the soluble aPS arms formed the shell. The miktoarm polymers aggregated to micro-nanoscale binary structures (MNBSes) in the casting process, and their morphologies, including the MNBS shape and size, were greatly influenced by the PxSy architectures. The MNBSes endowed the material surface with superhydrophobic performance with a water contact angle of 157.0 degrees and a sliding angle of 1.5 degrees.