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论文类型：期刊论文

发表时间：2009-03-01

发表刊物：JOURNAL OF ENVIRONMENTAL MONITORING

收录刊物：PubMed、SCIE、Scopus

卷号：11

期号：3

页面范围：648-653

ISSN号：1464-0325

摘要：An inorganic-organic hybrid fluorescence chemosensor (R6G-SBA-15) was prepared by covalent immobilization of a Rhodamine 6G derivative within the channels of mesoporous silica material SBA-15 via triethoxysilane groups. The primary hexagonally ordered mesoporous structure of SBA-15 is preserved after the grafting procedure. R6G- SBA-15 features effectively chromogenical and fluorogenical responses with a broad pH span (2-10), excellent sensitivity to environmentally relevant mercury levels lower to ppb range. It also exhibits Hg(2+)-specificity over various competitive cations, including alkali and alkaliearth, the first-row transition metals as well as heavy metals such as Pb(2+), Cd(2+) and Ag(+), etc. Additional experiments establish the well-fitted linearity function of the fluorescent intensity with the concentration of Hg(2+) in aqueous solution, suggesting the possibility for real-time qualitative or quantitative detection of Hg(2+) and the convenience for potential application in toxicology and environmental science.