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论文类型： 期刊论文

发表时间： 2019-11-02

发表刊物： ANALYTICAL LETTERS

收录刊物： SCIE

卷号： 52

期号： 16

页面范围： 2506-2523

ISSN号： 0003-2719

关键字： Cyclic voltammetry; differential pulse voltammetry; electrochemical impedance spectroscopy; gold nanoparticles; molecularly imprinted polymer; multiwalled carbon nanotubes; tetrabromobisphenol A

摘要： A sensitive and selective electrochemical sensor based on electropolymerized molecularly imprinted polypyrrole and gold nanoparticles-multiwalled carbon nanotubes (AuNPs-MWCNTs) hybrid nanocomposites was developed for the determination of tetrabromobisphenol A (TBBPA). A glassy carbon electrode (GCE) was modified with MWCNTs, and the AuNPs-MWCNTs/GCE was prepared by an electrodeposition method in HAuCl4 solution. The AuNPs-MWCNTs nanocomposite showed high electrocatalytic activity, good conductivity, and sufficient reactive sites for the direct electro-oxidation of TBBPA. The molecularly imprinted polymers (MIPs) as recognition elements were synthesized through in situ electro-polymerization of pyrrole as functional monomers in the presence of the TBBPA template molecules. Under the optimal conditions, the developed sensor exhibited good selectivity towards TBBPA compared with structural analogs, high sensitivity, and excellent producibility. The electrochemical responses of the sensor toward TBBPA were obtained in the linear range from 0.5 nM to 1 mu M with a limit of detection equal to 0.24 nM at a signal-to-noise ratio of 3.