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论文类型： 期刊论文

发表时间： 2018-03-01

发表刊物： AICHE JOURNAL

收录刊物： SCIE、EI

卷号： 64

期号： 3

页面范围： 981-992

ISSN号： 0001-1541

关键字： plasma chemistry; single molecular catalysis; hydrogen peroxide; synthesis; water

摘要： Direct synthesis of hydrogen peroxide (H2O2) from H-2 and O-2 is an ideal route. H-2/O-2 plasma has a great potential for direct synthesis of high purity H2O2 without purification operations. However, low yield and high energy consumption limits the application of H-2/O-2 plasma in industry. This article reports that gas state Ar and H2O molecule serving as molecular catalysts promoted the synthesis of H2O2 from H-2/O-2/Ar/H2O plasma dramatically: the H2O2 yield was enhanced by 244% and the energy consumption was reduced by 70.9%. Ar not only increased the electron density, but also selectively accelerated the dissociation of H-2 toward the formation of center dot HO2, a key intermediate species in H2O2 synthesis. While H2O facilitated the formation of center dot HO2 radical and stabilized it by forming a HO2 center dot H2O complex, resulting in enhancing the H2O2 production. This single molecular catalysis reduced the cost of H2O2 synthesis more than 50%. (C) 2017 American Institute of Chemical Engineers