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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：日本埼玉大学
学位：博士
所在单位：化工海洋与生命学院
学科：应用化学. 有机化学
办公地点：D01-309A
联系方式：0427-2631823
电子邮箱：Chem_wangwh@dlut.edu.cn
Mechanistic Insights into the Catalytic Hydrolysis of Ammonia Borane with Proton-Responsive Iridium Complexes: an Experimental and Theoretical Study
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论文类型：期刊论文
发表时间：2017-08-23
发表刊物：CHEMCATCHEM
收录刊物：SCIE、EI、Scopus
卷号：9
期号：16
页面范围：3191-3196
ISSN号：1867-3880
关键字：boranes; homogeneous catalysis; hydrogen; hydrolysis; iridium
摘要：For the homogeneous catalytic hydrolysis of ammonia borane (AB), a series of water-soluble proton-responsive iridium complexes bearing hydroxyl groups were utilized. Among the examined catalysts, [Cp*Ir(6,6'-(OH)(2)-bpy)(OH2)]SO4 exhibited the best catalytic performance in AB aqueous solution. Results obtained from experimental and theoretical studies revealed that hydrolysis of AB is assisted by synergistic effects between the pendent hydroxyl groups and the metal center.