Controlled Divinyl Monomer Polymerization Mediated by Lewis Pairs: A Powerful Synthetic Strategy for Functional Polymers
发表时间：2019-03-09
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- 论文类型：
- 期刊论文
- 第一作者：
- Jia, Yin-Bao
- 通讯作者：
- Lu, XB (reprint author), Dalian Univ Technol, State Key Lab Fine Chem, 2 Linggong Rd, Dalian 116024, Peoples R China.
- 合写作者：
- Ren, Wei-Min,Liu, Si-Jie,Xu, Tieqi,Wang, Yan-Bo,Lu, Xiao-Bing
- 发表时间：
- 2014-09-01
- 发表刊物：
- ACS MACRO LETTERS
- 收录刊物：
- SCIE、Scopus
- 文献类型：
- J
- 卷号：
- 3
- 期号：
- 9
- 页面范围：
- 896-899
- ISSN号：
- 2161-1653
- 摘要：
- Lewis pair cooperation provides a facile approach for polymerizing dissymmetric divinyl polar monomers such as 4-vinylbenzyl methacrylate in excellent regioselectivity and high reactivity at mild conditions, affording soluble polymers bearing pendant active vinyl groups with high molecular weight (up to 6.4 x 10(5) g/mol) and narrow polydispersity (PDI < 1.5). ESI-TOF MS study demonstrated that the polymerization process only concerned the methacrylic double bond and selectively remained the pendant allylic or styrene C=C bond.
- 是否译文：
- 否
