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Mechanistic Insights into the Catalytic Hydrolysis of Ammonia Borane with Proton-Responsive Iridium Complexes: an Experimental and Theoretical Study
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Indexed by:期刊论文

First Author:Wang, Wan-Hui

Correspondence Author:Li, Y (reprint author), Dalian Univ Technol, State Key Lab Fine Chem, Sch Petr & Chem Engn, 2 Dagong Rd, Liaodongwan New Dist 124221, Panjin, Peoples R China.; Himeda, Y (reprint author), Natl Inst Adv Ind Sci & Technol, Tsukuba Cent 5, Tsukuba, Ibaraki 3058565, Japan.

Co-author:Tang, Hui-Peng,Lu, Wen-Duo,Li, Yang,Bao, Ming,Himeda, Yuichiro

Date of Publication:2017-08-23

Journal:CHEMCATCHEM

Included Journals:SCIE、EI、Scopus

Volume:9

Issue:16

Page Number:3191-3196

ISSN No.:1867-3880

Key Words:boranes; homogeneous catalysis; hydrogen; hydrolysis; iridium

Abstract:For the homogeneous catalytic hydrolysis of ammonia borane (AB), a series of water-soluble proton-responsive iridium complexes bearing hydroxyl groups were utilized. Among the examined catalysts, [Cp*Ir(6,6'-(OH)(2)-bpy)(OH2)]SO4 exhibited the best catalytic performance in AB aqueous solution. Results obtained from experimental and theoretical studies revealed that hydrolysis of AB is assisted by synergistic effects between the pendent hydroxyl groups and the metal center.

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Associate Professor
Supervisor of Master's Candidates

Gender:Female

Alma Mater:辽宁师范大学

Degree:Doctoral Degree

School/Department:化工海洋与生命学院

Discipline:Applied Chemistry. Chemical Engineering. Fine Chemicals

Contact Information:chyangli@dlut.edu.cn

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