Indexed by:期刊论文

First Author:Sheong, Fu Kit

Correspondence Author:Lin, ZY (reprint author), Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China.

Co-author:Chen, Wen-Jie,Zhang, Jing-Xuan,Li, Yang,Lin, Zhenyang

Date of Publication:2017-01-01

Journal:DALTON TRANSACTIONS

Included Journals:SCIE、EI

Volume:46

Issue:7

Page Number:2214-2219

ISSN No.:1477-9226

Abstract:In this article, we have presented a computational analysis on the structure and bonding of [Pd2Sn18](4-)and illustrated that it serves as an interesting example of OMO-UMO mutual delocalisation with two identical [PdE9](2-) fragments. We have also illustrated the alternative roles that could be played by an [ME9](2-)/[E-9](2-) fragment, a simple L-type donor and a lone-pair acceptor.