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    乐天俊

    • 副教授      
    • 性别:男
    • 毕业院校:大连理工大学
    • 学位:博士
    • 所在单位:化工学院
    • 学科:应用化学. 精细化工
    • 办公地点:西部校区化工实验楼E330
    • 联系方式:0411-84708600
    • 电子邮箱:tjyue189@dlut.edu.cn

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    个人简介

           乐天俊 副教授,博士研究生导师。主要从事含硫聚合物精准合成方面的研究工作。具体为:以“无金属”催化的策略,实现含硫单体等参与的共聚反应,创制了系列具有高折射率的光学含硫聚合物;基于双金属协同催化策略,通过催化剂设计与合成,实现了含硫单体参与聚合反应的立体化学调控,创制了系列高立构规整度的含硫聚合物,提升材料的热学性能;通过多元聚合体系的开发,创制了拓扑结构的含硫聚合物,实现了含硫聚合物热、力以及光学性能的提升。以第一作者/通讯作者在Chem. Rev. (1 ), Angew. Chem. Int. Ed. (6 ), Macromolecular (5 ), Polym. Chem. (2 ), Eur. Polym. J. (1 ) 等期刊上发表学术论文15篇,累计参与发表学术论文共30余篇。授权中国发明专利11项,其中1项已完成专利使用授权许可。2018年入选中国科协中外优秀青年交流计划”,到美国Texas A&M University访学交流。2020年12月获工学博士学位。研究方向含硫聚合物的精准合成。2021年进入大连理工大学化学流动站,从事博士后研究工作。2021年入选“博士后创新人才支持计划”资助,并获“国家自然科学基金青年项目”以及“中国博士后科学基金面上项目”资助。

    科研项目:

    1. 《硫代酸酐与内消旋环硫烷烃的立体选择性共聚》国家自然科学基金青年科学基金项目,2022.01 ~ 2024.12,总经费30万(项目负责人)。

    2. 《手性聚硫代酯的精准合成》中国博士后科学基金博士后创新人才支持计划,2021.06 ~ 2023.06,总经费23万(项目负责人)。

    3. 《立构规整性聚硫代酯的精准合成》中国博士后科学基金面上项目,2021.06 ~ 2023.06,总经费8万(项目负责人)。

           4.  《手性环硫氯丙烷的合成技术》济南扬诺生物科技有限公司,2022.08 ~ 2024.09,总经费100万(项目负责人)。

    论文成果:

          [17] Jin-Zhuo Zhao,Tian-Jun Yue, Bai-Hao Ren, Xiao-Bing Lu, Wei-Min Ren*. Closed-loop recycling ofsulfur-rich polymers with tunable properties spanning thermoplastics, elastomers, and vitrimers. Nat. Commun. 2024, 153002−3009

          [16] Xiang-Yu Fu, Tian-Jun Yue*, Bai-Hao Ren, Hai Wang, Wei-Min Ren*, and Xiao-Bing Lu. A Powerful Strategy for Synthesizing Block Copolymers via Bimetallic Synergistic Catalysis. Angew. Chem. Int. Ed. 2024, 63e202401926.

         [15] Tian-Jun Yue, Xiang-Yu Fu, Ji Zhang, Yong-Gui Zhou, Wei-Min Ren,* and Xiao-Bing Lu. Elemental Selenium-Derived Poly(sulfide selenide)s: A Platform of Photodegradable and Electrochemical Responsive Polymers. Macromolecules 2024, 57, 1319−1327.

           [14] Yu Xiao, Tian-Jun Yue, Bai-Hao Ren, Wei-Min Ren,* and Xiao-Bing Lu. Isotactic-Rich Polythioethers Synthesized from Asymmetric Ring-Opening Polymerization of Racemic Terminal Thiiranes. ACS Catal. 202313, 16215−16221.

    [13] Tian-Jun Yue, Wei-Min Ren*, and Xiao-Bing Lu. Copolymerization involving sulfur-containing monomers. Chem. Rev. 2023, 123, 14038−14083.

    [12] Xiao-Hui Guo, Ge-Ge Gu, Tian-Jun Yue* and Wei-Min Ren. Orthogonal polymerization of aziridine with cyclic carbonates for constructing amphiphilic block copolymers. Polym. Chem. 202314, 5034–5039.

    [11] Tian-Jun Yue, Li-Yang Wang, Wei-Min Ren*, Xiao-Bing Lu. Regioselective copolymerization of epoxides and phthalic thioanhydride to produce isotacticity-rich semiaromatic polythioesters. Eur. Polym. J. 2023190, 111985–111992.

    [10] Jin-Zhuo Zhao, Tian-Jun Yue (first co-author), Bai-Hao Ren, Ye Liu, Wei-Min Ren*, Xiao-Bing Lu. Recyclable sulfur-rich polymers with enhanced thermal, mechanical, and optical performance. Macromolecules 202255, 8651–8658.

    [9] Ji-Yan Chao, Tian-Jun Yue (first co-author), Bai-Hao Ren, Ge-Ge Gu, Xiao-Bing Lu, Wei-Min Ren*. Controlled disassembly of elemental sulfur: An approach to the precise synthesis of polydisulfides. Angew. Chem. Int. Ed. 2022, 61, e202115950.

    [8] Tian-Jun Yue, Li-Yang Wang Wei-Min Ren*. The synthesis of degradable sulfur-containing polymers: precise control of structure and stereochemistry. Polym. Chem202112, 6650–6666.

    [7] Tian-Jun Yue, Bai-Hao Ren, Wen-Jian Zhang, Xiao-Bing Lu, Donald J. Darensbourg, Wei-Min Ren. Randomly distributed sulfur atoms in the main chains of CO2-based polycarbonates: Enhanced optical properties. Angew. Chem. Int. Ed. 202160, 4315–4321.

    [6] Tian-Jun Yue, Gulzar A. Bhat, Wen-Jian Zhang, Wei-Min Ren,* Xiao-Bing Lu, and Donald J. Darensbourg*. Facile synthesis of well-defined branched sulfur-containing copolymers: One-pot copolymerization of carbonyl sulfide and epoxide. Angew. Chem. Int. Ed202059, 13633–13637.

    [5] Tian-Jun Yue, Ming-Chao Zhang, Ge-Ge Gu, Li-Yang Wang, Wei-Min Ren,* Xiao-Bing Lu*. Precise synthesis of poly(thioester)s with diverse structures by copolymerization of cyclic thioanhydrides and episulfides mediated by organic ammonium salts. Angew. Chem. Int. Ed. 201958, 618–623.

    [4] Tian-Jun Yue, Wei-Min Ren,* Li Chen, Ge-Ge Gu, Ye Liu, Xiao-Bing Lu. Synthesis of chiral sulfur-containing polymers: Asymmetric copolymerization of meso-epoxides and carbonyl sulfide. Angew. Chem. Int. Ed. 201857, 12670–12674.

    [3] Wei-Min Ren,* Tian-Jun Yue, Ming-Ran Li, Zhao-Qian Wan, Xiao-Bing Lu. Crystalline and elastomeric poly(monothiocarbonate)s prepared from copolymerization of COS and achiral epoxide. Macromolecules 201750, 63−68.

    [2] Wei-Min Ren,* Tian-Jun Yue, Xue Zhang, Ge-Ge Gu, Ye Liu, Xiao-Bing Lu. Stereoregular CO2 copolymers from epoxides with an electron-withdrawing group: Crystallization and unexpected stereocomplexation. Macromolecules 201750, 7062–7069.

    [1] Tian-Jun Yue, Wei-Min Ren,* Ye Liu, Zhao-Qian Wan, Xiao-Bing Lu. Crystalline polythiocarbonate from stereoregular copolymerization of carbonyl sulfide and epichlorohydrin. Macromolecules 201649, 2971−2976.

     



    教育经历

    2005.9 -- 2010.6
    湖北省广水市文华高级中学       理科

    2010.9 -- 2014.6
    大连理工大学       应用化学       学士

    2014.9 -- 2020.12
    大连理工大学       应用化学       博士

    工作经历

    2019.2 -- 2020.2

    Texas A&M university      访问学者

    2021.3 -- 2023.9

    大连理工大学      博士后

    2023.10 -- 至今

    大连理工大学      副教授

    研究方向

  • 含硫聚合物、可降解高分子、配位聚合

  • 二氧化碳化学利用

  • 含硫聚合物的设计

  • 可降解性高分子材料