张光辉 (副教授)

副教授   博士生导师   硕士生导师

性别:男

毕业院校:武汉大学

学位:博士

在职信息:在职

所在单位:化工学院

电子邮箱:gzhang@dlut.edu.cn

   
   

个人简介

张光辉,博士,副教授,博士生导师,大连理工大学“星海青千”。2007年毕业于南京师范大学化学专业获学士学位;2010年毕业于南京师范大学有机化学专业孙培培教授课题组获硕士学位;2014年毕业于武汉大学有机化学专业雷爱文教授课题组获得博士学位。攻读博士学位期间曾于2012年-2014年在美国阿贡国家实验室合作研究。获得博士学位之后,曾先后在美国阿贡国家实验室/伊利诺伊理工学院化学系Adam S. Hock教授课题组(2014-2016年)、美国普渡大学化工学院Jeffrey T. Miller教授课题组(2016-2018年)任博士后研究员,并于2018年加入大连理工大学化工学院。


近年来主要利用动态、原位光谱学方法研究催化反应机理,探讨催化剂活性中心的结构与反应活性之间的构效关系。发表SCI论文80余篇,Wiley书籍1章。据Web of Science统计,论文被引1800余次,H因子为25。目前的研究兴趣主要集中在多相催化领域,尤其是二氧化碳、烷烃等小分子的催化转化。欢迎具有化学、化工、材料背景,对纳米材料、多相催化、表面金属有机化学、催化剂原位表征感兴趣的同学加入我们研究团队。


博士研究生招生专业:工业催化(学术博士)

硕士研究生招生专业:工业催化(学术硕士)、化学工程、材料与化工(专业硕士)

联系方式:gzhang@dlut.edu.cn


https://orcid.org/0000-0002-5854-6909

https://publons.com/researcher/1422154/guanghui-zhang/


Dr. Guanghui Zhang is an associate professor of chemical engineering at Dalian University of Technology. He obtained his B.S. in chemistry and M.S. in organic chemistry from Nanjing Normal University in 2007 and 2010, respectively. He received his PhD in chemistry at Wuhan University in 2014 (Prof. Aiwen Lei's group). From 2012 to 2014, he was a visiting graduate student at Argonne National Laboratory. In 2014, he joined Prof. Adam S. Hock's group at Illinois Institute of Technology/Argonne National Laboratory as a senior research associate, and in 2016, he moved to Purdue University working with Prof. Jeffrey T. Miller. He joined Dalian University of Technology in 2018. His research interest lies in heterogeneous catalysis, surface organometallic chemistry, and synchrotron-related X-ray spectroscopy. His current research focuses on the development of new catalytic materials for energy and environmental applications. 


MS, PhD and PostDoc positions are available. We are specifically looking for students who are interested in nanomaterials, heterogeneous catalysis, surface organometallic chemistry and in situ spectroscopic characterization. Inquiries should be sent to gzhang@dlut.edu.cn. 


Selected Publications 


  • Since 2018


  1. Zhang, X.; Zhang, G.*; Liu, W.; Yuan, F.; Wang, J.; Zhu, J.; Jiang, X.; Zhang, A.; Ding, F.; Song, C.*; Guo, X.*: Reaction-Driven Surface Reconstruction of ZnAl2O4 Boosts the Methanol Selectivity in CO2 Catalytic Hydrogenation. Appl. Catal. B: Environ. 2020, DOI: 10.1016/j.apcatb.2020.119700

  2. Yuan, F.; Zhang, G.*; Zhu, J.; Ding, F.; Zhang, A.; Song, C.*; Guo, X.*: Boosting light olefin selectivity in CO2 hydrogenation by adding Co to Fe catalysts within close proximity. Catal. Today 2020, DOI: 10.1016/j.cattod.2020.07.072 (Special issue in honor of Prof. Chunshan Song for receiving the George Olah Award)

  3. Zhu, J.; Zhang, G.*; Li, W.; Zhang, X.; Ding, F.; Song, C.*; Guo, X.*: Deconvolution of the Particle Size Effect on CO2 Hydrogenation over Iron-based Catalysts. ACS Catal. 2020, 10, 7424-7433

  4. Wan, G.; Zhang, G.*; Lin, X.-M.*: Toward Efficient Carbon and Water Cycles: Emerging Opportunities with Single-Site Catalysts Made of 3d Transition Metals. Adv. Mater. 2020, 32, 1905548

  5. Zhang, X.#; Han, S.#; Zhu, B.#; Zhang, G.#; Li, X.; Gao, Y.*; Wu, Z.; Yang, B.*; Liu, Y.; Baaziz, W.; Ersen, O.; Gu, M.*; Miller, J.T.; Liu, W.*: Reversible Loss of Core-shell Structure for Ni-Au Bimetallic Nanoparticles During CO2 Hydrogenation. Nat. Catal. 2020, 3, 411-417

  6. Wang, J.#; Liu, C.-Y.#; Senftle, T.P.; Zhu, J.; Zhang, G.*; Guo, X.*; Song, C.*: Variation in the In2O3 Crystal Phase Alters Catalytic Performance toward the Reverse Water Gas Shift Reaction. ACS Catal. 2020, 10, 3264-3273 (封面文章)

  7. Wegener, E.C.; Bukowski, B.C.; Yang, D.; Wu, Z.; Kropf, A.J.; Delgass, W.N.; Greeley, J.; Zhang, G.*; Miller, J.T.*: Intermetallic Compounds as an Alternative to Single-atom Alloy Catalysts: Geometric and Electronic Structures from Advanced X-ray Spectroscopies and Computational Studies. ChemCatChem 2020, 12, 1325-1333

  8. An, S.#; Zhang, G.#; Liu, J.; Li, K.*; Wan, G.; Liang, Y.; Ji, D.; Miller, J.T.; Song, C.; Liu, W.; Liu, Z.; Guo, X.*: A Facile Sulfur-Assisted Method to Synthesize Porous Alveolate Fe/g-C3N4 Catalysts with Ultra-small Cluster and Atomically Dispersed Fe Sites. Chin. J. Catal. 2020, 41, 1198-1207

  9. Zhang, G.#; Ye, C.#; Liu, W.; Zhang, X.; Su, D.; Yang, X.; Zhu Chen, J.; Wu, Z.*; Miller, J. T.*: Diffusion Limited Formation of Non-Equilibrium Intermetallic Nanophase for Selective Dehydrogenation. Nano Lett. 2019, 19, 4380-4383

  10. Cesar, L.G.; Yang, C.; Lu, Z.; Ren, Y.; Zhang, G.*; Miller, J.T.*: Identification of a Pt3Co Surface Intermetallic Alloy in Pt-Co Propane Dehydrogenation Catalysts. ACS Catal. 2019, 9, 5231-5244

  11. LiBretto, N.J.; Yang, C.; Ren, Y.; Zhang, G.*; Miller, J.T.*: Identification of Surface Structures in Pt3Cr Intermetallic Nanocatalysts. Chem. Mater. 2019, 31, 1597-1609

  12. Liu, J.; Zhang, A.; Jiang, X.; Zhang, G.*; Sun, Y.; Liu, M.; Ding, F.; Song, C.*; Guo, X.*: Overcoating the Surface of Fe-based Catalyst with ZnO and Nitrogen-doped Carbon toward High Selectivity of Light Olefins in CO2 Hydrogenation. Ind. Eng. Chem. Res. 2019, 58, 4017-4023

  13. ZhuChen, J.; Wu, Z.; Zhang, X.; Choi, S.; Xiao, Y.; Varma, A.; Liu, W.; Zhang, G.*; Miller, J.T.*: Identification of the Structure of the Bi Promoted Pt Non-oxidative Coupling of Methane Catalyst: A Nanoscale Pt3Bi Intermetallic Alloy. Catal. Sci. Technol. 2019, 9, 1349-1356 (封面文章)

  14. Yang, C.; Wu, Z.; Zhang, G.*; Sheng, H.; Tian, J.; Duan, Z.; Sohn, H.; Kropf, A.J.; Wu, T.; Krause, T.R.; Miller, J.T.*: Promotion of Pd Nanoparticles by Fe and Formation of a Pd3Fe Intermetallic Alloy for Propane Dehydrogenation. Catal. Today 2019, 323, 123-128 (Special Issue Honoring Prof. Umit S. Ozkan: 2017 ACS Henry H. Storch Award Winner)

  15. Wu, Z.; Bukowski, B. C.; Li, Z.; Milligan, C.; Zhou, L.; Ma, T.; Wu, Y.; Ren, Y.; Ribeiro, F. H.; Delgass, W. N.; Greeley, J.; Zhang, G.*; Miller, J. T.*: Changes in Catalytic and Adsorptive Properties of 2 nm Pt3Mn Nanoparticles by Subsurface Atoms. J. Am. Chem. Soc. 2018, 140, 14870-14877

  16. Shen, X.#; Zhang, C.#; Zhang, S.#; Dai, S.#; Zhang, G.#; Ge, M.#; Pan, Y.; Sharkey, S.; Graham, G.; Hunt, A.; Waluyo, I.*; Miller, J. T.*; Pan, X.*; Peng, Z.*: Deconvolution of octahedral Pt3Ni nanoparticle growth pathway from in situ characterizations. Nat. Commun. 2018, 9, 4485

  17. An, S.#; Zhang, G.#; Wang, T.; Zhang, W.; Li, K.*; Song, C.; Miller, J.T.; Miao, S.; Wang, J; Guo, X.*: High-Density Untrasmall Cluster and Single-atom Fe Sites Embedded in g-C3N4 for Highly Efficient Catalytic Advanced Oxidation Processes. ACS Nano 2018, 12, 9441-9450

  18. Ye, C.#; Wu, Z.#; Liu, W.; Ren, Y.; Zhang, G.*; Miller, J.T.*: Structure Determination of a Surface Tetragonal Pt1Sb1 Phase on Pt Nanoparticles. Chem. Mater. 2018, 30, 4503-4507

  19. Zhang, G.; Yang, C.; Miller, J.T.*: Tetrahedral Nickel(II) Phosphosilicate Single Site Selective Propane Dehydrogenation Catalyst. ChemCatChem 2018, 10, 961-964


  • Before 2018

  1. Zhang, G.; Yi, H.; Xin, J.; Deng, Y.; Bai, R. P.; Huang, Z. L.; Miller, J. T.; Kropf, A. J.; Bunel, E. E.; Qi, X. T.; Lan, Y.; Lei, A. W.*: Aromatic C-H Bond Cleavage by Using a Cu(I) Ate-Complex. Org. Chem. Front. 2016, 3, 975-978

  2. Yi, H.#; Zhang, G.#; Xin, J.; Deng, Y.; Miller, J. T.; Kropf, A. J.; Bunel, E. E.; Qi, X. T.; Lan, Y.; Lee, J.-F.; Lei, A. W.*: Homolytic Cleavage of O-Cu(II) bond: XAFS and EPR Spectroscopy Evidence for One Electron Reduction of Cu(II) to Cu(I). Chem. Commun. 2016, 52, 6914-6917

  3. Deng, Y.#; Zhang, G.#; Qi, X. T.; Liu, C.; Miller, J. T.; Kropf, A. J.; Bunel, E. E.; Lan, Y.*; Lei, A. W.*: Revealing the Halide Effect on the Kinetics of the Aerobic Oxidation of Cu(I) to Cu(II). Chem. Commun. 2015, 51, 318-321.

  4. Zhang, G.#; Yi, H.#; Zhang, G. T.; Deng, Y.; Bai, R. P.; Zhang, H.; Miller, J. T.; Kropf, A. J.; Bunel, E. E.; Lei, A. W.*: Direct Observation of Reduction of Cu(II) to Cu(I) by Terminal Alkynes. J. Am. Chem. Soc. 2014, 136, 924-926.

  5. Zhang, G.; Li, J.; Deng, Y.; Miller, J. T.; Kropf, A. J.; Bunel, E. E.; Lei, A. W.*: Structure-kinetic Relationship Study of Organozinc Reagents. Chem. Commun. 2014, 50, 8709-8711.

  6. Zhang, G.; Chou, H.-H.; Jiang, X.; Sun, P.*; Cheng, C.-H.: Highly Efficient White Organic Light-Emitting Diodes Based on Broad Excimer Emission of Iridium Complex. Org. Electron. 2010, 11, 1165-1171.

  7. Zhang, G.; Chou, H.-H.; Jiang, X.; Sun, P.*; Cheng, C.-H.; Ooyama, Y.; Harima, Y.: Highly Efficient Organic Light-Emitting Diodes (OLEDs) Based on an Iridium Complex with Rigid Cyclometalated Ligand. Org. Electron. 2010, 11, 632-640.

  8. Zhang, G.; Li, X.; Jiang, X.; Sun, P.*: Impact of Substituents in the N^N Ligand on the Emission Wavelength of Cu(I) Complexes: Insight from Experimental and Theoretical Approach. J. Lumin. 2010, 130, 976-980.

  9. Zhang, G.; Wu, F.-I.; Jiang, X.; Sun, P.*; Cheng, C.-H.: Iridium(III) Complexes with Cyclometalated Styrylbenzoimidazole Ligands: Synthesis, Electrochemistry and as Highly Efficient Emitters for Organic Light-Emitting Diodes. Synt. Met. 2010, 160, 1906-1911.


教育经历

[1]   2010.9-2014.12

武汉大学  |  有机化学  |  博士

[2]   2007.9-2010.6

南京师范大学  |  有机化学  |  硕士

[3]   2003.9-2007.7

南京师范大学  |  化学  |  学士

工作经历

[1]   2018.8-至今

大连理工大学  |  副教授

[2]   2016.9-2018.8

美国普渡大学  |  博士后研究员

[3]   2014.10-2016.5

美国伊利诺伊理工大学  |  高级研究助理

社会兼职

  • [1]   2019.9-至今    
    Associate Editor(Frontiers in Chemical Engineering)