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  • 张光辉

    的个人主页 http://faculty.dlut.edu.cn/zhangguanghui/zh_CN/index.htm

个人简介


张光辉博士于2007年毕业于南京师范大学化学专业获学士学位;2010年毕业于南京师范大学有机化学专业孙培培教授课题组获硕士学位;2014年毕业于武汉大学有机化学专业雷爱文教授课题组获得博士学位。攻读博士学位期间曾于2012年-2014年在美国阿贡国家实验室合作研究。获得博士学位之后,曾先后在美国伊利诺伊理工大学化学系Adam S. Hock教授课题组、普渡大学化工系Jeffrey T. Miller教授课题组任博士后研究员,并于2018年加入大连理工大学化工与环境生命学部任副教授。


张光辉博士近年来主要利用原位光谱学方法研究催化反应机理,探讨催化剂活性中心的结构与反应活性之间的构效关系,在均相催化、多相催化领域都有丰富的研究经验和基础。相关研究结果建立了若干催化反应中催化活性位点与催化反应活性之间的构效关系,为新型催化剂的设计、合成提供了重要的理论依据和指导。在页岩气催化转化领域的研究方面也有重要的发现,发展了一系列新型高效的页岩气转化双金属及单原子催化剂,为提高页岩气资源的高效利用提供了新的突破。在J Am Chem Soc、Angew Chem Int Ed、Nature Commun、Chem、Chem Sci、Chem Commun、ACS Nano、Chem Mater、ACS Catal、J Catal等化学、催化领域内的国际期刊上发表SCI论文50逾篇,Wiley书籍1章。据Web of Science统计,到2018年9月论文已被引800逾次,个人H因子为18。


张光辉博士目前的研究兴趣主要集中在多相催化领域,尤其是二氧化碳、烷烃等小分子的催化转化。


https://orcid.org/0000-0002-5854-6909

http://www.researcherid.com/rid/C-4747-2008


联系方式:gzhang@dlut.edu.cn


Publications


  1. Wright, A. M.; Wu, Z.; Zhang, G.; Mancuso, J. L.; Comito, R. J.; Day, R. W.; Hendon, C. H.; Miller, J. T.; Dinca, M.: A Structural Mimic of Carbonic Anhydrase in a Metal-Organic Framework. Chem 2018, accepted, DOI: 10.1016/j.chempr.2018.09.011

  2. Yang, C.; Wu, Z.; Zhang, G.; Sheng, H.; Tian, J.; Duan, Z.; Sohn, H.; Kropf, A.J.; Wu, T.; Krause, T.R.; Miller, J.T.: Promotion of Pd nanoparticles by Fe and formation of a Pd3Fe intermetallic alloy for propane dehydrogenation. Catal. Today, 2018, Accepted, DOI: 10.1016/j.cattod.2018.07.043 (corresponding author)

  3. Wu, Z.; Bukowski, B. C.; Li, Z.; Milligan, C.; Zhou, L.; Ma, T.; Wu, Y.; Ren, Y.; Ribeiro, F. H.; Delgass, W. N.; Greeley, J.; Zhang, G.; Miller, J. T.: Changes in Catalytic and Adsorptive Properties of 2 nm Pt3Mn Nanoparticles by Subsurface Atoms. J. Am. Chem. Soc. 2018, 140, 14870-14877 (corresponding author)

  4. Joshi, R.; Zhang, G.; Miller, J. T.; Gounder, R.: Evidence for the Coordination-Insertion Mechanism of Ethene Dimerization at Nickel Cations Exchanged onto Beta Molecular Sieves. ACS Catal. 2018, 8, 11407-114

  5. Shen, X.; Zhang, C.; Zhang, S.; Dai, S.; Zhang, G.; Ge, M.; Pan, Y.; Sharkey, S.; Graham, G.; Hunt, A.; Waluyo, I.; Miller, J. T.; Pan, X.; Peng, Z.: Deconvolution of octahedral Pt3Ni nanoparticle growth pathway from in situ characterizations. Nature Commun., 2018, 9. 4485 (co-first author)

  6. An, S.; Zhang, G.; Wang, T.; Zhang, W.; Li, K.; Song, C.; Miller, J.T.; Miao, S.; Wang, J; Guo, X.: High-Density Untrasmall Cluster and Single-atom Fe Sites Embedded in g-C3N4 for Highly Efficient Catalytic Advanced Oxidation Processes. ACS Nano, 2018, 12, 9441-9450 (co-first author)

  7. Ye, C.; Wu, Z; Liu, W.; Ren, Y.; Zhang, G.; Miller, J.T.: Structure Determination of a Surface Tetragonal Pt1Sb1 Phase on Pt Nanoparticles. Chem. Mater., 2018, 30, 4503-4507 (corresponding author)

  8. Zhang, G.; Yang, C.; Miller, J. T.: Tetrahedral Nickel(II) Phosphosilicate Single Site Selective Propane Dehydrogenation Catalyst. ChemCatChem, 2018, 10, 961-964

  9. Comito, R.; Wu, Z.; Zhang, G.; Lawrence, J.; Korzynski, M.; Kehl, J. A.; Miller, J.T.; Dinca, M.:  Stabilized Vanadium Catalyst for Olefin Polymerization by Site Isolation in a Metal‐Organic Framework. Angew. Chem. Int. Ed. 2018, 57, 8135-8139

  10. Jackson, M.N.; Oh, S.; Kaminsky, C.J.; Chu, S.B.; Zhang, G.; Miller, J.T.; Surendranath, Y.: Strong Electronic Coupling of Molecular Sites to Graphitic Electrodes via Pyrazine Conjugation. J. Am. Chem. Soc. 2018, 140, 1004-1010

  11. Liu, K.; Zhang, C.; Sun, Y.; Zhang, G.; Shen, X.; Zou, F.; Zhang, H.; Wu, Z.; Wegener, E.C.; Taubert, C.J.; Miller, J.T.; Peng, Z.; Zhu, Y.: High-Performance Transition Metal Phosphide Alloy Catalyst for Oxygen Evolution Reaction. ACS Nano 2018, 12, 158-167

  12. Su, Z.; Miao, Y.-R.; Zhang, G.; Miller, J. T.; Suslick, K. S.: Bond breakage under pressure in a metal organic framework. Chem. Sci. 2017, 8, 8004-8011

  13. Huang, Z.; Liu, D.; Camacho-Bunquin, J.; Zhang, G.; Yang, D.; Lopez-Encarnacion, J. M.; Xu, Y.; Ferrandon, M. S.; Niklas, J.; Poluektov, O. G.; Jellinek, J.; Lei, A.; Bunel, E. E.; Delferro, M.: Supported single-site Ti(IV) on a metal-organic framework for the hydroboration of carbonyl compounds. Organometallics 2017, 36, 3921-3930

  14. Dubey, R.; Comito, R. J.; Wu, Z.; Zhang, G.; Rieth, A. J.; Hendon, C. H.; Miller, J. T.; Dincă, M.: Highly Stereoselective Heterogeneous Diene Polymerization by Co-MFU-4l: A Single-Site Catalyst Prepared by Cation Exchange. J. Am. Chem. Soc. 2017, 139, 12664-12669

  15. Comito, R. J.; Metzger, E. D.; Wu, Z.; Zhang, G.; Hendon, C. H.; Miller, J. T.; Dincă, M.: Selective Dimerization of Propylene with Ni-MFU-4l. Organometallics 2017, 36, 1681-1683

  16. Cybulskis, V.J.; Pradhan, S.U.; Lovon-Quintana, J.J.; Hock, A.S.; Hu, Bo.; Zhang, G.; Delgass, W.N.; Ribeiro, F.H.; Miller, J.T.: The Nature of the Isolated Gallium Active Center for Propane  Dehydrogenation on Ga/SiO2. Catal. Lett. 2017, 147, 1252-1262

  17. Pichaandi, K.R.; Kabalan, L.; Amini, H.; Zhang, G.; Zhu, H.; Kenttämaa, H.I.; Fanwick, P.E.; Miller, J.T.; Kais, S.; Nabavizadeh, S.M.; Rashdi M.; Abu-Omar, M.M.: Mechanism of Me-Re Bond Addition to Platinum(II) and Dioxygen Activation by the Resulting Pt–Re Bimetallic Center. Inorg. Chem., 2017, 56, 2145-2152

  18. Zhang, G.; Yi, H.; Xin, J.; Deng, Y.; Bai, R. P.; Huang, Z. L.; Miller, J. T.; Kropf, A. J.; Bunel, E. E.; Qi, X. T.; Lan, Y.; Lei, A. W.: Aromatic C-H Bond Cleavage by Using a Cu(I) Ate-Complex. Org. Chem. Frontiers, 2016, 3, 975-978

  19. Yi, H.; Zhang, G.; Xin, J.; Deng, Y.; Miller, J. T.; Kropf, A. J.; Bunel, E. E.; Qi, X. T.; Lan, Y.; Lee, J.-F.; Lei, A. W.: Homolytic cleavage of O-Cu(II) bond: XAFS and EPR spectroscopy evidence for one electron reduction of Cu(II) to Cu(I). Chem. Commun. 2016, 52, 6914-6917 (co-first author)

  20. Liu, P.; Zhang, G.; Sun, P.: Transition metal-free decarboxylative alkylation reactions. Org. Biomol. Chem. 2016, 14, 10763-10777

  21. Getsoian, A.; Das, U.; Bunquin, J. C.; Zhang, G.; Gallagher, J. R.; Hu, B.; Cheah, S.; Schaidle, J. A.; Ruddy, D. A.; Hensley, J. E.; Krause, T. R.; Curtiss, L. A.; Miller, J. T.; Hock, A. S.: Organometallic Model Complexes Elucidate the Active Gallium Species in Alkane Dehydrogenation Catalysts Based on Ligand Effects in Ga K-edge XANES. Catal. Sci. Technol. 2016, 6, 6339-6353

  22. Yi, H.; Liao, Z.X.; Zhang, G.; Zhang, G.T.; Fan, C.; Zhang, X.; Bunel, E.E.; Pao, C.-W.; Lee, J.-F.; Lei, A.: Evidence of CuI/CuII Redox Process by X-ray Absorption and EPR Spectroscopy: Direct Synthesis of Dihydrofurans from β-Ketocarbonyl Derivatives and Olefins. Chem Eur. J. 2015, 21, 18925-18929

  23. Yuan, J. W.; Wang, J.; Zhang, G.; Liu, C.; Qi, X. T.; Lan, Y.; Miller, J. T.; Kropf, A. J.; Bunel, E. E.; Lei, A. W.: Bimetallic zinc complex - active species in coupling of terminal alkynes with aldehydes via nucleophilic addition/Oppenauer oxidation. Chem. Commun. 2015, 51, 576-579.

  24. Su, Z.; Miao, Y.-R.; Mao, S.-M.; Zhang, G.; Dillon, S.; Miller, J. T.; Suslick, K. S.: Compression-Induced Deformation of Individual Metal–Organic Framework Microcrystals. J. Am. Chem. Soc. 2015, 137, 1750-1753.

  25. Schaidle, J. A.; Ruddy, D. A.; Habas, S. E.; Pan, M.; Zhang, G.; Miller, J. T.; Hensley, J. E.: Conversion of Dimethyl Ether to 2,2,3-Trimethylbutane over a Cu/BEA Catalyst: Role of Cu Sites in Hydrogen Incorporation. ACS Catal. 2015, 1794-1803.

  26. Qi, X.; Li, Y.; Zhang, G.; Li, Y.; Lei, A.; Liu, C.; Lan, Y.: Dinuclear versus mononuclear pathways in zinc mediated nucleophilic addition: a combined experimental and DFT study. Dalton Trans. 2015, 44, 11165-11171.

  27. Hu, B.; Schweitzer, N. M.; Zhang, G.; Kraft, S. J.; Childers, D. J.; Lanci, M. P.; Miller, J. T.; Hock, A. S.: Isolated FeII on Silica As a Selective Propane Dehydrogenation Catalyst. ACS Catal. 2015, 5, 3494-3503.

  28. Gu, W.; Stalzer, M. M.; Nicholas, C. P.; Bhattacharyya, A.; Motta, A.; Gallagher, J. R.; Zhang, G.; Miller, J. T.; Kobayashi, T.; Pruski, M.; Delferro, M.; Marks, T. J.: Benzene Selectivity in Competitive Arene Hydrogenation: Effects of Single-Site Catalyst···Acidic Oxide Surface Binding Geometry. J. Am. Chem. Soc. 2015, 137, 6770-6780.

  29. Duan, H.; Li, M.; Zhang, G.; Gallagher, J. R.; Huang, Z.; Sun, Y.; Luo, Z.; Chen, H.; Miller, J. T.; Zou, R.; Lei, A.; Zhao, Y.: Single-Site Palladium(II) Catalyst for Oxidative Heck Reaction: Catalytic Performance and Kinetic Investigations. ACS Catal. 2015, 5, 3752-3759.

  30. Camacho-Bunquin, J.; Siladke, N. A.; Zhang, G.; Niklas, J.; Poluektov, O. G.; Nguyen, S. T.; Miller, J. T.; Hock, A. S.: Synthesis and Catalytic Hydrogenation Reactivity of a Chromium Catecholate Porous Organic Polymer. Organometallics 2015, 34, 947-952.

  31. Lu, Q.; Liu, Z.; Luo, Y.; Zhang, G.; Huang, Z.; Wang, H.; Liu, C.; Miller, J. T.; Lei, A.: Copper-/Cobalt-Catalyzed Highly Selective Radical Dioxygenation of Alkenes. Org. Lett. 2015, 17, 3402-3405.

  32. Lu, Q.; Zhang, J.; Peng, P.; Zhang, G.; Huang, Z.; Yi, H.; Miller, J. T.; Lei, A.: Operando X-ray absorption and EPR evidence for a single electron redox process in copper catalysis. Chem. Sci. 2015, 6, 4851-4854.

  33. Madrahimov, S. T.; Gallagher, J. R.; Zhang, G.; Meinhart, Z.; Garibay, S. J.; Delferro, M.; Miller, J. T.; Farha, O. K.; Hupp, J. T.; Nguyen, S. T.: Gas-phase dimerization of ethylene under mild conditions catalyzed by MOF materials containing (bipy)NiII complexes. ACS Catal. 2015, 5, 6713-6718

  34. Das, U.; Zhang, G.; Hu, B.; Hock, A.S.; Redfern, P.C.; Miller, J.T.; Curtiss, L.A.: Effect of Siloxane Ring Strain and Cation Charge Density on the Formation of Coordinately Unsaturated Metal Sites on Silica: Insights from Density Functional Theory (DFT) Studies. ACS Catal. 2015, 5, 7177-7185

  35. Wu, K.; Huang, Z.L.; Qi, X.T.; Li, Y.Z.; Zhang, G.; Liu, C.; Yi, H.; Meng, L.K.; Bunel, E.E.; Miller, J.T.; Pao, C.-W.; Lee, J.-F.; Lan, Y.; Lei, A.: Copper-catalyzed aerobic oxidative coupling: From ketone and diamine to pyrazine. Science Advance 2015, 1, e1500656

  36. Xin, J.; Zhang, G.; Deng, Y.; Zhang, H.; Lei, A.: Which one is faster? A kinetic investigation of Pd and Ni catalyzed Negishi-type oxidative coupling reactions. Dalton Trans. 2015, 44, 19777-19781

  37. Deng, Y.; Zhang, G.; Qi, X. T.; Liu, C.; Miller, J. T.; Kropf, A. J.; Bunel, E. E.; Lan, Y.; Lei, A. W.: Revealing the halide effect on the kinetics of the aerobic oxidation of Cu(I) to Cu(II). Chem. Commun. 2015, 51, 318-321. (co-first author)

  38. Zhang, G.; Yi, H.; Zhang, G. T.; Deng, Y.; Bai, R. P.; Zhang, H.; Miller, J. T.; Kropf, A. J.; Bunel, E. E.; Lei, A. W.: Direct Observation of Reduction of Cu(II) to Cu(I) by Terminal Alkynes. J. Am. Chem. Soc. 2014, 136, 924-926.

  39. Zhang, G.; Li, J.; Deng, Y.; Miller, J. T.; Kropf, A. J.; Bunel, E. E.; Lei, A. W.: Structure-kinetic relationship study of organozinc reagents. Chem. Commun. 2014, 50, 8709-8711.

  40. Li, W.; Liu, C.; Zhang, H.; Ye, K.; Zhang, G.; Zhang, W.; Duan, Z.; You, S.; Lei, A.: Palladium-Catalyzed Oxidative Carbonylation of N-Allylamines for the Synthesis of β-Lactams. Angew. Chem. Int. Ed. 2014, 53, 2443-2446.

  41. Zhang, H.; Lei, Y.; Kropf, A. J.; Zhang, G.; Elam, J. W.; Miller, J. T.; Sollberger, F.; Ribeiro, F.; Akatay, M. C.; Stach, E. A.; Dumesic, J. A.; Marshall, C. L.: Enhancing the stability of copper chromite catalysts for the selective hydrogenation of furfural using ALD overcoating. J. Catal. 2014, 317, 284-292.

  42. Kraft, S. J.; Zhang, G.; Childers, D.; Dogan, F.; Miller, J. T.; Nguyen, S. T.; Hock, A. S.: Rhodium Catechol Containing Porous Organic Polymers: Defined Catalysis for Single-Site and Supported Nanoparticulate Materials. Organometallics 2014, 33, 2517-2522.

  43. Krogman, J. P.; Gallagher, J. R.; Zhang, G.; Hock, A. S.; Miller, J. T.; Thomas, C. M.: Assignment of the oxidation states of Zr and Co in a highly reactive heterobimetallic Zr/Co complex using X-ray absorption spectroscopy (XANES). Dalton Trans. 2014, 43, 13852-13857.

  44. Tanabe, K. K.; Ferrandon, M. S.; Siladke, N. A.; Kraft, S. J.; Zhang, G.; Niklas, J.; Poluektov, O. G.; Lopykinski, S. J.; Bunel, E. E.; Krause, T. R.; Miller, J. T.; Hock, A. S.; Nguyen, S. T.: Discovery of Highly Selective Alkyne Semihydrogenation Catalysts Based on First-Row Transition-Metallated Porous Organic Polymers. Angew. Chem. Int. Ed. 2014, 53, 12055-12058.

  45. Bai, R.; Zhang, G.; Yi, H.; Huang, Z.; Qi, X.; Liu, C.; Miller, J. T.; Kropf, A. J.; Bunel, E. E.; Lan, Y.; Lei, A.: Cu(II)-Cu(I) Synergistic Cooperation to Lead the Alkyne C-H Activation. J. Am. Chem. Soc. 2014, 136, 16760-16763.

  46. Meng, L.; Zhang, G.; Liu, C.; Wu, K.; Lei, A.: Trifluoromethanesulfonic Acid Catalyzed Synergetic Oxidative/[3+2] Cyclization of Quinones with Olefins. Angew. Chem. Int. Ed. 2013, 52, 10195-10198.

  47. He, C.; Zhang, G.; Ke, J.; Zhang, H.; Miller, J. T.; Kropf, A. J.; Lei, A.: Labile Cu(I) Catalyst/Spectator Cu(II) Species in Copper-Catalyzed C-C Coupling Reaction: Operando IR, in Situ XANES/EXAFS Evidence and Kinetic Investigations. J. Am. Chem. Soc. 2013, 135, 488-493.

  48. Kraft, S. J.; Hu, B.; Zhang, G.; Miller, J. T.; Hock, A. S.: In Situ X-ray Absorption Spectroscopy and Nonclassical Catalytic Hydrogenation with an Iron(II) Catecholate Immobilized on a Porous Organic Polymer. Eur. J. Inorg. Chem. 2013, 2013, 3972-3977.

  49. Zhang, G.; Chou, H.-H.; Jiang, X.; Sun, P.; Cheng, C.-H.: Highly efficient white organic light-emitting diodes based on broad excimer emission of iridium complex. Org. Electron. 2010, 11, 1165-1171.

  50. Zhang, G.; Chou, H.-H.; Jiang, X.; Sun, P.; Cheng, C.-H.; Ooyama, Y.; Harima, Y.: Highly efficient organic light-emitting diodes (OLEDs) based on an iridium complex with rigid cyclometalated ligand. Org. Electron. 2010, 11, 632-640.

  51. Zhang, G.; Li, X.; Jiang, X.; Sun, P.: Impact of substituents in the N^N ligand on the emission wavelength of Cu(I) complexes: Insight from experimental and theoretical approach. J. Lumin. 2010, 130, 976-980.

  52. Zhang, G.; Wu, F.-I.; Jiang, X.; Sun, P.; Cheng, C.-H.: Iridium(III) complexes with cyclometalated styrylbenzoimidazole ligands: Synthesis, electrochemistry and as highly efficient emitters for organic light-emitting diodes. Synt. Met. 2010, 160, 1906-1911.

  53. Li, C.; Zhang, G.; Shih, H.-H.; Jiang, X.; Sun, P.; Pan, Y.; Cheng, C.-H.: High-efficient phosphorescent iridium(III) complexes with benzimidazole ligand for organic light-emitting diodes: Synthesis, electrochemistry and electroluminescent properties. J. Organomet. Chem. 2009, 694, 2415-2420.

  54. Hu, J.; Zhang, G.; Shih, H.-H.; Jiang, X.; Sun, P.; Cheng, C.-H.: Synthesis of a highly phosphorescent emitting iridium(III) complex and its application in OLEDs. J. Organomet. Chem. 2008, 693, 2798-2802.

  55. Hu, J.; Zhang, G.; Shih, H.-H.; Sun, P.; Cheng, C.-H.: Synthesis and luminescent properties of Ir complexes with fluorine substituted phenylpyridine derivative ligands. Synt. Met. 2008, 158, 912-916.

教育经历
  • 2010.9 -- 2014.12

    武汉大学       有机化学       博士

  • 2007.9 -- 2010.6

    南京师范大学       有机化学       硕士

  • 2003.9 -- 2007.7

    南京师范大学       化学       学士

工作经历
  • 2018.8 -- 至今

    大连理工大学      副教授

  • 2016.9 -- 2018.8

    美国普渡大学      博士后研究员

  • 2014.10 -- 2016.5

    美国伊利诺伊理工大学      高级研究助理

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