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    张树深

    • 研究员     博士生导师   硕士生导师
    • 性别:男
    • 毕业院校:北京师范大学
    • 学位:硕士
    • 所在单位:环境学院
    • 电子邮箱:zhangss@dlut.edu.cn

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    Carbon nitride with electron storage property: Enhanced exciton dissociation for high-efficient photocatalysis

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    论文类型:期刊论文

    发表时间:2018-11-15

    发表刊物:APPLIED CATALYSIS B-ENVIRONMENTAL

    收录刊物:SCIE、Scopus

    卷号:236

    页面范围:99-106

    ISSN号:0926-3373

    关键字:Carbon nitride; Electron storage; Excitonic effect; Exciton dissociation; Artificial photosynthesis

    摘要:Excitonic effect, originated from the strong Coulomb attraction between electron and hole, plays an important role in the photocatalytic process of polymeric materials but has been long ignored. In view point of hot-carriers generation, the dissociation of Frenkel excitons is proposed as an effective way to improve the photocatalytic performance of polymeric photocatalysts. Herein, by taking graphitic carbon nitride (g-C3N4) as an example, we verify that endowing g-C3N4 with electron storage ability can facilitate exciton dissociation by extracting electrons from bound electron-hole couples around the electron stotage sites, therefore enhancing the hot-carriers harvest and suppressing the charge recombination. Benefiting from these advantages, the as-prepared material demonstrates excellent photocatalytic performance for both H-2 evolution and H2O2 generation. As a result, the apparent quantum yield (AQY) for H-2 evolution at 420 nm reaches 55%, which is much higher than most of the reported polymeric materials. The study described here offers a new way for designing advanced polymeric photocatalysts toward high performance solar energy conversion via excitonic engineering.