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    张毅

    • 教授     博士生导师   硕士生导师
    • 性别:男
    • 毕业院校:清华大学
    • 学位:博士
    • 所在单位:能源与动力学院
    • 学科:能源与环境工程
    • 电子邮箱:zhangyi80@dlut.edu.cn

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    In situ observations by magnetic resonance imaging for formation and dissociation of tetrahydrofuran hydrate in porous media

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    论文类型:期刊论文

    发表时间:2011-02-01

    发表刊物:MAGNETIC RESONANCE IMAGING

    收录刊物:Scopus、SCIE、PubMed

    卷号:29

    期号:2

    页面范围:281-288

    ISSN号:0730-725X

    关键字:Tetrahydrofuran hydrate; Porous media; Formation; Dissociation; MRI

    摘要:Tetrahydrofuran (THF) hydrate has long been used as a substitute for methane hydrate in laboratory studies. This article investigated the formation and dissociation characteristics of THF hydrate in porous media simulated by various-sized quartz glass beads. The formation and dissociation processes of THF hydrate are observed using magnetic resonance imaging (MRI) technology. The hydrate saturation during the formation is obtained based on the MRI data. The experimental result suggests that the third surface has an effect on hydrate formation. THE hydrate crystals lean to form on the glass beads and in their adjacent area as well as from the wall of the sample container firstly. Furthermore, as the pore size diminishes, or as the formation temperature decreases, the nucleation gets easier and the formation processes faster. However, the dissociation rate is mostly dependent on the dissociation temperature rather than on the pore size. (C) 2011 Elsevier Inc. All rights reserved.