论文类型：期刊论文

发表时间：2008-03-01

发表刊物：SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY

收录刊物：SCIE、EI、PubMed

卷号：69

期号：3

页面范围：776-781

ISSN号：1386-1425

关键字：OH radicals; N-2(+) ions; spatially resolved spectra; pulsed streamer discharge; vibrational temperature

摘要：Optical emission spectroscopy has been applied to study the spatially resolved measurements of the emission intensities of OH (A(2)Sigma -> X-2 Pi, 0-0) and N-2(+) (B-2 Sigma E-u(+) -> X-2 Sigma(+)(g), 0-0, 391.4 nm) produced by a high-voltage positive pulsed streamer discharge consisting of a gas mixture of N-2 and H2O in a wire-plate reactor under severe electromagnetic interference at atmospheric pressure. The effects of pulse peak voltage, pulse repetition rate, and the added O-2 flow rate on the spatial distributions of the emission intensity of OH (A(2)Sigma -> X-2 Pi, 0-0) and N-2(+) (B-2 Sigma(+)(u) -> X-2 Sigma(+)(g), 0-0, 391.4 nm) in the lengthwise direction (direction from wire to plate) are investigated. It has been found that the emission intensities of OH (A(2)Sigma -> X-2 Pi, 0-0) and N-2(+) (B-2 Sigma(+)(u) -> X-2 Sigma(+)(g), 0-0, 391.4 nm) rise with an increase in both pulse peak voltage and pulse repetition rate and decrease with an increase in oxygen flows added in an N-2 and H2O gas mixture. The emission intensity of OH (A(2)Sigma -> X-2 Pi, 0-0) decreases with increasing the distance from the wire electrode. The emission intensity of N-2(+) (B-2 Sigma(+)(u) -> X-2 Sigma(+)(g), 0-0, 391.4 nm) is nearly constant at 0-4 mm from wire electrode, and sharply increases near the ground electrode. The vibrational temperature of N2 (C) increases with increasing 02 flows and keeps almost constant in the lengthwise direction under the present experimental conditions. The main physicochemical processes involved are also discussed in this paper. (c) 2007 Elsevier B.V. All rights

发表时间：2008-03-01