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个人信息Personal Information
高级工程师
硕士生导师
性别：女
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：应用化学
办公地点：理工西部校区实验楼F308
联系方式：rzhang@dlut.edu.cn
电子邮箱：rzhang@dlut.edu.cn
Recyclable alkylated Ru(bpy)(3)(2+) complex as a visible-light photoredox catalyst for perfluoroalkylation
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论文类型：期刊论文
发表时间：2018-04-12
发表刊物：TETRAHEDRON
收录刊物：SCIE
卷号：74
期号：15
页面范围：1742-1748
ISSN号：0040-4020
关键字：Coumarin; Perfluoroalkylation; Visible light; Recoverable photocatalyst
摘要：A recyclable Ruthenium tris [4,4'-bis (dinonylmethyl)-2,2'-bipyridine] (Ru[(DNM)(2)bpy](3)(2+)) photocatalyst (PC) was synthesized. Hexane-phase-selective solubility allowed its simple and efficient separation from reaction products via solvent extraction. The excellent catalytic activity and recoverability were demonstrated in batch and flow perfluoroalkylation reactions of coumarin under visible-light irradiation. High reaction rates and easy reusability of the catalyst make this approach attractive for large-scale applications. (C) 2018 Elsevier Ltd. All rights reserved.