论文成果
Recyclable alkylated fac-Ir(ppy)(3) complex as a visible-light photoredox catalyst for the synthesis of 3-trifluoromethylated and 3-difluoroacetylated coumarins
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- 论文类型：期刊论文
- 发表时间：2018-12-20
- 发表刊物：TETRAHEDRON
- 收录刊物：SCIE、Scopus
- 文献类型：J
- 卷号：74
- 期号：51
- 页面范围：7358-7363
- ISSN号：0040-4020
- 关键字：Photocatalysis; Thermomorphic multicomponent solvent; Catalyst recycle;
Trifluoromethylation; Difluroacetylation
- 摘要：A recyclable fac-tris(heptadecanyl-2-phenylpyridine) iridium [fac-Ir(hdppy)(3)] photocatalyst was synthesized. The hexane-phase-selective solubility of fac-Ir(hdppy)(3) in a thermomorphic multicomponent solvent (TMS) allowed its easy recycling by automatic liquid/liquid separation at room temperature. The excellent catalytic and recoverable activities of fac-Ir(hdppy)(3) were demonstrated via trifuoromethylation and difluoroacetylation reactions of phenyl 3-phenylpropiolate under visible-light irradiation in a TMS system. (C) 2018 Elsevier Ltd. All rights reserved.
