张蓉

个人信息Personal Information

高级工程师

硕士生导师

性别:女

毕业院校:大连理工大学

学位:博士

所在单位:化工学院

学科:应用化学

办公地点:理工西部校区实验楼F308

联系方式:rzhang@dlut.edu.cn

电子邮箱:rzhang@dlut.edu.cn

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Copper-mediated oxidative trifluoromethylthiolation of aryl boronic acids with CF3CO2Na and elemental sulfur

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论文类型:期刊论文

发表时间:2013-12-02

发表刊物:TETRAHEDRON

收录刊物:SCIE、Scopus

卷号:69

期号:48

页面范围:10262-10266

ISSN号:0040-4020

关键字:Copper-mediated; Oxidation; Trifluoromethylthiolation; Sodium trifluoroacetate; Synthetic methods

摘要:A practical three-component copper-mediated oxidative trifluoromethylthiolation of aryl boronic acids with cheap and readily available sodium trifluoroacetate and elemental sulfur is reported. A variety of trifluoromethylthio-substituted aromatics are synthesized in moderate yields under mild reaction conditions. (C) 2013 Elsevier Ltd. All rights reserved.