|
个人信息Personal Information
高级工程师
硕士生导师
性别：女
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：应用化学
办公地点：理工西部校区实验楼F308
联系方式：rzhang@dlut.edu.cn
电子邮箱：rzhang@dlut.edu.cn
扫描关注
Nickel-catalyzed C-H direct amination of benzoxazoles with secondary amines
点击次数：
论文类型：期刊论文
发表时间：2012-05-14
发表刊物：ORGANIC & BIOMOLECULAR CHEMISTRY
收录刊物：SCIE、EI、PubMed、Scopus
卷号：10
期号：18
页面范围：3715-3720
ISSN号：1477-0520
摘要：In this article, a facile, efficient and practical method for Ni-catalyzed direct C-H amination of benzoxazole with secondary amines has been developed. This procedure requires Ni(OAc)(2)center dot 4H(2)O as catalyst, TBHP as oxidant and acid as the additive. Avariety of substituted benzoxazol-2-amines were synthesized in moderate to good yields.