王金渠

个人信息Personal Information

教授

博士生导师

硕士生导师

性别:男

毕业院校:大连工学院

学位:硕士

所在单位:化工学院

电子邮箱:wjinqu@dlut.edu.cn

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Synthesis of 4-Substituted Styrene Compounds via Palladium-Catalyzed Suzuki Coupling Reaction Using Free Phosphine Ligand in Air

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论文类型:期刊论文

发表时间:2010-01-01

发表刊物:SYNTHETIC COMMUNICATIONS

收录刊物:SCIE

卷号:40

期号:2

页面范围:196-205

ISSN号:0039-7911

关键字:4-Substituted styrene compounds; Schiff base ligands; Suzuki; synthesis

摘要:The air-stable and easy to prepare nonsymmetric Schiff base ligands have been synthesized and proven to be efficient ligands for Suzuki cross-coupling reaction between aryl bromides and arylboronic acids using PdCl2(CH3CN)2 as palladium source under aerobic conditions. The coupling reaction proceeded smoothly using N-[(3,4-dimethoxyphenyl)methylene]-1,2-benzenediamine (L3) as ligand under mild conditions to provide 4-substituted styrene compounds in good yields.