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One-pot strategy for covalent construction of POSS-modified silane layer on carbon fiber to enhance interfacial properties and anti-hydrothermal aging behaviors of PPBES composites
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论文类型: 期刊论文
发表时间: 2018-12-01
发表刊物: JOURNAL OF MATERIALS SCIENCE
收录刊物: SCIE、Scopus
卷号: 53
期号: 24
页面范围: 16303-16317
ISSN号: 0022-2461
关键字: Bond strength (chemical); Carbon fibers; Contact angle; Dynamics; Shear strength; Silanes; Tensile strength; Wetting, 3-aminopropyltriethoxysilane; Copoly (phthalazinone ether sulfone); Dynamic contact angle; Dynamic mechanical property; Inter-laminar shear strengths; Interfacial adhesions; Interfacial property; Separation and purification, Failure (mechanical)
摘要: In this study, we describe a novel strategy to design and construct POSS-modified silane layer on carbon fiber (CF) to strengthen the interfacial adhesion and anti-hydrothermal aging behaviors of CF-reinforced copoly(phthalazinone ether sulfone)s (PPBES). POSS was first modified by 3-aminopropyltriethoxysilane (APS) to improve chemical reactivity. Without separation and purification, APS-c-POSS was used to functionalize CF to improve reactivity and ensure the covalent linkages between CF and POSS-modified silane layer. CF coated with POSS-modified silane layer was obtained by in situ hydrolysis of APS-c-POSS. FTIR and XPS confirmed the chemical bonds between CF and POSS-modified silane layer. Dynamic contact angle, dynamic wetting test and AFM tests demonstrated that POSS-modified silane coating can increase the wettability and roughness, which could improve interlaminar shear strength and flexural strength of CF/PPBES composites by 17.5 and 30.0% with slight enhancement on tensile strength of CF. The failure mechanisms of CF/PPBES composites with and without POSS-modified silane layer were both investigated by SEM in detail. Moreover, this layer was helpful to dynamic mechanical property and hydrothermal resistance of CF/PPBES composites. This study provides alternate strategy to modify CF with POSS, which will significantly broaden the application field of POSS in advanced composites.

蹇锡高

教授   博士生导师   硕士生导师

性别: 男

毕业院校:大连工学院

学位: 硕士

所在单位:化工学院

学科:高分子材料. 高分子化学与物理. 膜科学与技术

联系方式:手机:13904286124

电子邮箱:jian4616@dlut.edu.cn

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