- Optimization and characterization of poly(phthalazinone ether ketone) (PPEK) heat-resistant porous fiberous mat by electrospinning
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- 论文类型： 期刊论文
- 发表时间： 2016-08-30
- 发表刊物： APPLIED SURFACE SCIENCE
- 收录刊物： SCIE、EI、Scopus
- 卷号： 379
- 页面范围： 282-290
- ISSN号： 0169-4332
- 关键字： Electrospinning Fibrous mat; Heat-resistance; N-2 adsorption; Mechanical behaviors
- 摘要： Poly(phthalazinone ether ketone) (PPEK) is noted for its outstanding heat-resistance property and mechanical strength. A one-step electrospinning method was conducted to produce PPEK micro-nano porous fibrous mat. We gave emphasis study on the spinnability, optimized conditions, fibers' morphology, surface science and fracture mechanism. The uniform electrospun fibrous mat resulted from PPEK/chloroform binary system indicated that PPEK would be a prospective material to be applied in electrospinning. Addition of a small amount of non-solvent (ethanol) turned out to be advantageous to the reduction of fiber diameter and the alleviation of choking during spinning process. Organic salt (benzyltrimethylammonium chloride) was employed to increase the conductivity of solution for the formation of thin fiber. After trials, PPEK/chloroform/ethanol system with salt and PPEK/NMP system were taken as two optimized systems. These two systems showed different pore fraction in N-2 adsorption test, and displayed different mechanical behaviors in uniaxial tension test. The fibrous mat from PPEK/chloroform/ethanol system showed a feature of ductile fracture with relatively low fracture strength but long fracture deformation, while the fibrous mat from PPEK/NMP system showed a feature of brittle fracture with small deformation but quite large fracture strength of ca. 6 MPa. Finally thermogravimetric analysis indicated that the resultant PPEK fibrous mat did not decompose until the temperature reached 478 degrees C, which qualified the resultant fibrous mat as a promising material used under high-temperature condition. (C) 2016 Elsevier B.V. All rights reserved.
