- Nickel-catalysed Kumada polycondensation of di-functionalized Grignard reagent with aryl fluoride
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- 论文类型： 期刊论文
- 发表时间： 2016-05-01
- 发表刊物： POLYMER INTERNATIONAL
- 收录刊物： SCIE、EI、Scopus
- 卷号： 65
- 期号： 5
- 页面范围： 526-534
- ISSN号： 0959-8103
- 关键字： Kumada polycondensation; nickel-catalysed; di-functionalized oligothiophene Grignard reagent; phenyl-s-triazine; aryl fluoride
- 摘要： A nickel catalyst promoted the polymerization between various Grignard reagents with 2-phenyl-4,6-bi(4-fluorophenyl)-1,3,5-triazine. The reaction scope was thoroughly investigated and fully characterized. The Sp(2)-C - F bond was successfully activated by the triazine group in Kumada coupling reactions. Also, di-Grignard reagents showed higher activity than mono-Grignard reagents. The reaction scope results reveal that a Grignard reagent with strong nucleophilicity and aryl fluoride with strong electrophilicity are necessary to lead to Kumada polycondensation of oligothiophenes with aryl fluoride. In this work, polymerization between di-functionalized oligothiophene Grignard reagents with aryl fluoride was first conducted. The weight-average molecular weight is high, up to 14.8 kDa. The -conjugated polymers obtained exhibit emission colours of blue, green and yellow with efficient photoluminescence. (c) 2016 Society of Chemical Industry
