- Synthesis and characterization of star-comb styrene/butadiene copolymer
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- 论文类型: 期刊论文
- 发表时间: 2010-11-01
- 发表刊物: CHINESE CHEMICAL LETTERS
- 收录刊物: SCIE、ISTIC、CSCD、Scopus
- 卷号: 21
- 期号: 11
- 页面范围: 1370-1373
- ISSN号: 1001-8417
- 关键字: Anionic polymerization; Epoxidation; Grafting reaction; Star-comb copolymer; Side chain
- 摘要: A novel star-comb styrene/butadiene copolymer (SC-SBC) was synthesized by anionic polymerization and grafting reaction with epoxidized star liquid polybutadiene (ESPB) as coupling agent. The overall shape of the star-comb macromolecules can be altered by changing the molecular weight and number of the side chain. The molecular parameters and mechanical properties of the SC-SBC resins were investigated. The notched izod impact strength of the SC-SBC resins are excellent and reach as high as to 239 J/m. (C) 2010 Yang Li. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.