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Lyotropic liquid crystalline poly(aryl ether ketone) copolymer containing phthalazinone moiety and biphenyl mesogen
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发布时间: 2019-03-10
发布时间:2019-03-10
论文类型:期刊论文
发表时间:2007-08-01
发表刊物:EUROPEAN POLYMER JOURNAL
收录刊物:Scopus、EI、SCIE
卷号:43
期号:8
页面范围:3683-3687
ISSN号:0014-3057
关键字:copolymerization; liquid-crystalline polymers (LCP); lyotropic; poly(ether ketones); phthalazinone
摘要:A novel lyotropic liquid crystalline material poly(aryl ether ketone) copolymer containing phthalazinone moiety and biphenyl mesogen named P-8515 was developed by a mild solution polycondensation method, The molecular weight (M-n) was 53,000 and the value of molecular weight distribution index (MDI) was 2.49 detected by GPC. The critical concentration (C*) of P-8515 was 36 wt% and P-8515 exhibited characteristic nematic lyotropic liquid crystalline phases in NMP solution at different concentrations and the phase morphology changed to a typical threaded texture when shear forces were induced from PLM observations. The T-g value was 238 degrees C and the value for 5% weight loss temperature was 515 degrees C in nitrogen from DSC and TGA determinations, respectively. (c) 2007 Elsevier Ltd. All rights reserved.

蹇锡高

教授   博士生导师   硕士生导师

性别: 男

毕业院校:大连工学院

学位: 硕士

所在单位:化工学院

学科:高分子材料. 高分子化学与物理. 膜科学与技术

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