- Synthesis and properties of novel aromatic copolyamides derived from 2-(4-carboxyphenyl)-4-[3-phenyl-4-(4-carboxyphenoxyl) phenyl]-phthalazinone
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- 论文类型： 期刊论文
- 发表时间： 2006-12-01
- 发表刊物： HIGH PERFORMANCE POLYMERS
- 收录刊物： SCIE、EI、Scopus
- 卷号： 18
- 期号： 6
- 页面范围： 867-876
- ISSN号： 0954-0083
- 关键字： copolyamides; phthalazinone; solubility; thermal properties; tensile properties
- 摘要： A series of four novel aromatic copolyamides were synthesized by the direct polycondensation of 2-(4-carboxyphenyl)-4-[3-phenyl-4-(4-carboxyphenoxyl)phenyl]-phthalazinone (1) and terephthalic acid (TPA) with some commercial diamines. The inherent viscosities of the polyamides were between 0.91 and 2.77 dL g(-1). All the copolyamides showed an amorphous nature as evidenced by wide-angle X-ray diffraction. Introduction of the non-coplanar phthalazinone segments into the polymer main chains remarkably improved the solubility of aromatic copolyamides. Most of the copolymers were soluble in aprotic polar solvents, such as N-methyl-pyrrolidone (NMP), N,N-dimethylacetamide, and dimethylsulfoxide. These aromatic copolyamides showed high thermal properties associated with the glass transition temperatures (T-g) in the range of 261-307 degrees C and 10% weight loss temperatures in N-2 over 481 degrees C. Moreover, the T-g values of the copolyamides increased with the increasing ratio of phthalazinone moiety in the main chain. Some polymer films cast from NMP solution had tensile strengths up to 244.4 MPa, initial moduli up to 5.08 GPa, and elongation at break values up to 9.9%.
