- Heteropolymolybdate as a new reaction-controlled phase-transfer catalyst for efficient alcohol oxidation with hydrogen peroxide
- 点击次数：
- 论文类型： 期刊论文
- 发表时间： 2006-06-01
- 发表刊物： CHINESE CHEMICAL LETTERS
- 收录刊物： SCIE、ISTIC、Scopus
- 卷号： 17
- 期号： 6
- 页面范围： 848-850
- ISSN号： 1001-8417
- 关键字： heteropolymolybdate; reaction-controlled phase-transfer; alcohol; oxidation
- 摘要： A new catalytic process for the synthesis of aldehyde from alcohol by oxidation with H2O2 with high selectivity was studied. In this system, heteropolymolybdate [C7H7N(CH3)(3)](3) {PO4[MoO(O-2)(2)](4)} was utilized as the reaction-controlled phase-transfer catalyst to catalyze oxidation of benzyl and aliphatic alcohols. The molar ratio of H2O2 and alcohol was 0.75, no other by-products were detected by gas chromatography, the results of oxidation reaction indicated that the catalyst has high activity and stability.
