大连理工大学主页平台管理系统蹇锡高连续纤维增强聚芳醚砜酮复合材料的性能中文主页

论文成果

Heteropolymolybdate as a new reaction-controlled phase-transfer catalyst for efficient alcohol oxidation with hydrogen peroxide: 点击次数：; 发布时间： 2019-03-10; 发布时间：2019-03-10; 论文类型：期刊论文; 发表时间：2006-06-01; 发表刊物：CHINESE CHEMICAL LETTERS; 收录刊物：Scopus、ISTIC、SCIE; 卷号：17; 期号：6; 页面范围：848-850; ISSN号：1001-8417; 关键字：heteropolymolybdate; reaction-controlled phase-transfer; alcohol; oxidation; 摘要：A new catalytic process for the synthesis of aldehyde from alcohol by oxidation with H2O2 with high selectivity was studied. In this system, heteropolymolybdate [C7H7N(CH3)(3)](3) {PO4[MoO(O-2)(2)](4)} was utilized as the reaction-controlled phase-transfer catalyst to catalyze oxidation of benzyl and aliphatic alcohols. The molar ratio of H2O2 and alcohol was 0.75, no other by-products were detected by gas chromatography, the results of oxidation reaction indicated that the catalyst has high activity and stability.

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教授博士生导师硕士生导师

性别：男

毕业院校：大连工学院

学位：硕士

所在单位：化工学院

学科：高分子材料. 高分子化学与物理. 膜科学与技术

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