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Synthesis of new soluble polyarylates containing phthalazinone moiety
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发布时间: 2019-03-10
发布时间:2019-03-10
论文类型:期刊论文
发表时间:2006-01-01
发表刊物:CHINESE CHEMICAL LETTERS
收录刊物:ISTIC、SCIE
卷号:17
期号:1
页面范围:140-142
ISSN号:1001-8417
关键字:polyarylates; phthalazinone; solubility; thermal behavior
摘要:A novel diacid chloride, 2-(4-chlorocarboxyphenyl)-4-[3,5-dimethyl-4-(4-chlorocarboxylphenoxy)phenyl]-2,3-phthalazin- 1-one 2, was synthesized and used for the preparation of polyarylates with inherent viscosities of 0.25-0.37 dL center dot g(-1). The glass transition temperatures of polyarylates were in the range of 217-272 degrees C. The temperatures at 10% weight loss of polyarylates were found to be in the range of 434-464 degrees C in nitrogen atmosphere and their structure was confirmed by FTIR and H-1 NMR. The amorphous polyarylates exhibited excellent solubility in a variety of solvents such as NMP, DMAc, DMF and chloroform.

蹇锡高

教授   博士生导师   硕士生导师

性别: 男

毕业院校:大连工学院

学位: 硕士

所在单位:化工学院

学科:高分子材料. 高分子化学与物理. 膜科学与技术

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