- Synthesis of new soluble polyarylates containing phthalazinone moiety
- 点击次数：
- 论文类型： 期刊论文
- 发表时间： 2006-01-01
- 发表刊物： CHINESE CHEMICAL LETTERS
- 收录刊物： SCIE、ISTIC
- 卷号： 17
- 期号： 1
- 页面范围： 140-142
- ISSN号： 1001-8417
- 关键字： polyarylates; phthalazinone; solubility; thermal behavior
- 摘要： A novel diacid chloride, 2-(4-chlorocarboxyphenyl)-4-[3,5-dimethyl-4-(4-chlorocarboxylphenoxy)phenyl]-2,3-phthalazin- 1-one 2, was synthesized and used for the preparation of polyarylates with inherent viscosities of 0.25-0.37 dL center dot g(-1). The glass transition temperatures of polyarylates were in the range of 217-272 degrees C. The temperatures at 10% weight loss of polyarylates were found to be in the range of 434-464 degrees C in nitrogen atmosphere and their structure was confirmed by FTIR and H-1 NMR. The amorphous polyarylates exhibited excellent solubility in a variety of solvents such as NMP, DMAc, DMF and chloroform.
