- A new reaction-controlled phase-transfer catalyst system
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- 论文类型： 期刊论文
- 发表时间： 2004-03-01
- 发表刊物： CHINESE CHEMICAL LETTERS
- 收录刊物： Scopus、SCIE、ISTIC
- 卷号： 15
- 期号： 3
- 页面范围： 350-352
- ISSN号： 1001-8417
- 关键字： reaction-controlled phase-transfer catalyst; cyclohexene; epoxidation
- 摘要： A new reaction-controlled phase-transfer catalyst system was designed and synthesized. In this system, heteropolytungstate [C7H7N(CH3)(3)](9)PW9O34 was used for catalytic epoxidation of cyclohexene with H2O2 as the oxidant. The conversion of H2O2 was 100% and the yield of cyclohexene oxide was 87.1% based on cyclohexene. Infrared spectra showed that both fresh catalyst and the recovered catalyst do have completely same absorption peak, indicating the structure of catalyst is very stability and can be recycled.
