- Synthesis and characterization of sulfonated poly(phthalazinone ether ketone) for proton exchange membrane materials
- 点击次数：
- 论文类型： 期刊论文
- 发表时间： 2003-02-15
- 发表刊物： JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
- 收录刊物： Scopus、SCIE、EI
- 卷号： 41
- 期号： 4
- 页面范围： 497-507
- ISSN号： 0887-624X
- 关键字： poly(phthalazinone ether ketone); sulfonation; proton exchange membranes; fuel cell; poly(ether ketones); ionomers; membranes
- 摘要： As a novel class of proton exchange membrane materials for use in fuel cells, sulfonated poly(phthalazinone ether ketone)s (SPPEKs) were prepared by the modification of poly(phthalazinone ether ketone). Sulfonation reactions were conducted at room temperature with mixtures of 95-98% concentrated sulfuric acid and 27-33% fuming sulfuric acid with different acid ratios, and SPPEK was obtained with a degree of sulfonation (DS) in the desired range of 0.6-1.2. The presence of sulfonic acid groups in SPPEK was confirmed by Fourier transform infrared analysis, and the DS and structures were characterized by NMR. The introduction of sulfonic groups into the polymer chains increased the glass-transition temperature above the decomposition temperature and also led to an overall decrease in the decomposition temperature. Membrane films were cast from SPPEK solutions in N,N-dimethylacetamide. Water uptakes and swelling ratios of SPPEK membrane films increased with DS, and SPPEKs with DS > 1.23 were water-soluble at 80 degreesC. Proton conductivity increased with DS and temperature up to 95 C, reaching 10(-2)S/cm. (C) 2003 Wiley Periodicals, Inc.
