- Synthesis of poly (aryl amide imide)s derived from o-diphenyltrimellitic anhydride
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- 论文类型: 期刊论文
- 发表时间: 2002-09-01
- 发表刊物: JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION
- 收录刊物: Scopus、SCIE
- 卷号: 17
- 期号: 3
- 页面范围: 90-93
- ISSN号: 1000-2413
- 关键字: poly(aryl amide imide)s; o-diphenyltrimellitic acid; synthesis
- 摘要: The synthesis and characterization of a series of novel poly (aryl amide imide) s based on o-diphenyltrimellitic anhydride are described. The poly(aryl amide-imide) s having inherent viscosities of 0.39 - 1. 43 dL/g in N-methyl-2-pyrrolidinone at 30degreesC, were prepared by polymerization with aromatic diamines in N, N - dimethylacetamide and subsequent chemical imidization. All the polymers were amorphous, readily soluble in aprotic polar solvents such as DMAC, NMP, DMF, DMSO, and m-cresol, and could be cast to form flexible and tough films. The glass trsanition temperatures were in the range of 284 - 336degreesC, and the temperatures for 5% weight loss in nitrogen were above 468degreesC.