- Preparation and characterization of soluble copoly(aryl ether ketone)s containing hindering structures
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- 论文类型: 期刊论文
- 发表时间: 2000-10-03
- 发表刊物: JOURNAL OF APPLIED POLYMER SCIENCE
- 收录刊物: Scopus、SCIE、EI
- 卷号: 78
- 期号: 1
- 页面范围: 20-24
- ISSN号: 0021-8995
- 关键字: polycondensation; copoly(aryl ether ketone); chain structure; property; solubility
- 摘要: New copoly(aryl ether ketone)s have been synthesized by polycondensation of 2,2',3,3',6,6'-hexaphenyl-4,4'-diphenol, 2,2'-p-hydroxyphenyl-iso-propane, and 4,4'-difluorobenzophenone. The technology of C-13-NMR was used to determine contents of the two bisphenols in the copolymers. Chain structure was characterized by illustrating average block length (L-A, L-C) in terms of portion of the triads (AKA, CKC, AKC). The obtained copoly(aryl ether ketone)s have the properties of excellent solubility, high heat-resistance, good tensile strength, and good selectivity for gas permeability. (C) 2000 John Wiley & Sons, Inc.