大连理工大学主页平台管理系统蹇锡高 Synthesis and characterization of poly(ether amide)s containing phthalazinone moieties 中文主页

论文成果

Synthesis and characterization of poly(ether amide)s containing phthalazinone moieties: 点击次数：; 发布时间： 2019-03-10; 发布时间：2019-03-10; 论文类型：期刊论文; 发表时间：2000-02-01; 发表刊物：CHEMICAL RESEARCH IN CHINESE UNIVERSITIES; 收录刊物：CSCD、SCIE; 卷号：16; 期号：1; 页面范围：78-82; ISSN号：1005-9040; 关键字：phthalazinone; diacid; diamine; polyamide; direct polycondensation; 摘要：Soluble aromatic polyamides containing phthalazinone moieties were prepared. Those polymers were obtained from the solution polymerization of a new diacid containing phthalazinone moieties with various diamines. The new monomer, 2-(4-carboxyphenyl)-4-(4-carboxyphenoxy) phenyl-1 (2H) phthalazinone (IV) was synthesized in a two-step reaction sequence. 2-(4-Cyanophenyl)-4-(4-cyanophenoxy)phenyl-1 (2H) phthalazinone (III) was prepared via the condensation reaction of 4-(4-hydroxyphenyl)-1 (2H) phthalazinone (I) with p-chlorobenzonitrile (II). After (III) was hydrolyzed, (IV) was-acquired. The synthesized polyamides were characterized by means of viscosimetry, DSC, FT-IR, H-1 NMR and EA. The polyamides have a high glass transition temperature which can be as high as 316 degrees C. The polyamides also have good solubilities in same organic solvents.

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教授博士生导师硕士生导师

性别：男

毕业院校：大连工学院

学位：硕士

所在单位：化工学院

学科：高分子材料. 高分子化学与物理. 膜科学与技术

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