- Synthesis of all-aromatic polyamides containing the 1,2-dihydro-4-phenyl(2H)phthalazinone moiety
- 点击次数:
- 论文类型: 期刊论文
- 发表时间: 1999-06-01
- 发表刊物: JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
- 收录刊物: Scopus、SCIE、EI
- 卷号: 37
- 期号: 11
- 页面范围: 1565-1567
- ISSN号: 0887-624X
- 关键字: phthalazinone; diamine; polyamides; direct polycondensation
- 摘要: The direct polycondensations of 1,2-dihydro-2-(4-aminophenyl)-4-[4-(4-aminophenoxyl) phenyl](2H)phthalazin-1-one with three aromatic diacids were carried out using Yamazaki phosphorylation method. The high molecular weight polyamides were obtained in quantitative yields. The polyamides exhibited high glass transition temperatures which were typically over 310 °C. The three polyamides were readily soluble in polar aprotic solvents such as N-methylpyrrolidone, N,N-dimethylformamide, dimethylacetamide, dimethyl sulfoxide, and pyridine.