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发布时间：2019-03-13

论文类型：期刊论文

发表时间：2019-01-30

发表刊物：INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

收录刊物：Scopus、SCIE

卷号：58

期号：4

页面范围：1525-1534

ISSN号：0888-5885

关键字：Catalysts; Catalytic oxidation; Ion exchange; Nitrates; Oxidation; Oxygen vacancies; Ozone; Ozone water treatment; Ozonization; Paramagnetic resonance, Catalytic ozonation; Exchange-time; Iron nitrates; Liquid ion exchange; Low concentrations; NO oxidation; Structure and properties; Superoxide radical, Iron oxides

摘要：A series of SAPO-34 supported iron oxide (FeOx/SAPO-34) catalysts were prepared by a two-step liquid ion-exchange method. The effects of the exchange time and iron nitrate concentration on the structure and properties of the catalysts were investigated. The results showed that the FeOx/SAPO-34 catalysts significantly enhanced the ozonation of NO. The 0.05-FeOx/SAPO-34-15 catalyst prepared by mixing NH4+/SAPO-34 with 0.05 M iron nitrate solution for 15 h showed the most effective NO oxidation. Oxygen vacancies acted as the active sites for the catalytic oxidation of NO. The electron paramagnetic resonance results showed that the hydroxyl and superoxide radicals generated from ozone and the oxygen vacancies on the surface of the catalysts promoted the oxidation of NO. The 0.05-FeOx/SAPO-34-15 catalyst has a certain stability when the volume fraction of water vapor is in the range 0-8%.