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论文类型： 期刊论文

发表时间： 2015-01-01

发表刊物： CHEMICAL ENGINEERING JOURNAL

收录刊物： SCIE、EI、ESI高被引论文

卷号： 259

页面范围： 814-819

ISSN号： 1385-8947

关键字： Forward osmosis; Hyaluronic acid/polyvinyl alcohol; Electric-responsive hydrogel; Draw agent

摘要： Recently, many materials have been evaluated as draw agents for forward osmosis (FO) processes. In the present work, it is the first attempt to regard electric-responsive polymer hydrogels as draw agents in an FO process. Electric-responsive hyaluronic acid/polyvinyl alcohol (HA/PVA) polymer hydrogels have been prepared by repeated freezing-thawing. Polymer hydrogels with different freezing-thawing cycles were designated as HA-PVA-3, HA-PVA-5, HA-PVA-7, and HA-PVA-9, respectively. The effects of freezing-thawing cycle, voltage, and concentrations of the feed solution on the FO process were examined, while the as-prepared polymer hydrogels were used as draw agents. By using HA-PVA-5, HA-PVA-7, and HAPVA-9 polymer hydrogels as draw agents and deionised water as the feed solution in FO process, the initial water fluxes reached 1.2, 0.91, and 0.9 L m(-2) h(-1), respectively. When the voltage of the electric field was 0, 3, 6, and 9 V, the total water fluxes produced by HA-PVA-5 polymer hydrogels in 24 h reached 17.27, 20.95, 25.49, and 26.47 L m(-2), respectively. When the different concentrations of sodium chloride was used as feed solutions, the total water fluxes produced by HA-PVA-5 polymer hydrogels at a voltage of 6 V in 24 h were recorded at 22.66, 15.77, and 12.41 L m(-2) for 2000, 5000 and 8000 ppm, respectively. Compared with the other published studies which also adopted polymer hydrogels as draw agents in FO process, the fluxes in our article are desirable. In addition, salt reverse diffusion of the draw agent can be avoided and the complexity of the operation can be minimized when the electric-responsive hydrogels are employed as draw agents in FO process. (C) 2014 Elsevier B.V. All rights reserved.