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发布时间：2019-03-09

论文类型：期刊论文

发表时间：2014-09-15

发表刊物：JOURNAL OF HAZARDOUS MATERIALS

收录刊物：Scopus、PubMed、EI、SCIE

卷号：280

页面范围：20-30

ISSN号：0304-3894

关键字：Polyaniline; Cellulose acetate; Hg(II); Cr(VI); Adsorption

摘要：Conductive composite membrane-phytic acid (PA) doped polyaniline (PANI)/cellulose acetate (CA) (PANI-PA/CA) was prepared in a simple and environmental-friendly method, in which aniline was blended with CA/PA solution and polymerized before the phase conversion. The resultant composite membranes were characterized by SEM, EDX, FTIR-ATR, BET and electrical resistance measurements. When used as adsorbent for Hg(II) and Cr(VI) ions, the prepared composite membrane exhibits excellent adsorption capability. The adsorption of Hg(II) and Cr(VI) follows a pseudo-second-order kinetic model and best fits the Langmuir isotherm model, with the maximum adsorption capacity reaching 280.11 and 94.34 mg g(-1), respectively. The heavy metal loaded composite membrane can be regenerated and reused after treatment with acid or alkali solution, making it a promising and practical adsorbent for Hg(II) and Cr(VI) removal. Tests with river water were also carried out, indicating good performance and application. (C) 2014 Elsevier B.V. All rights reserved.