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杨凤林
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性别: 男

毕业院校: 大连工学院

学位: 硕士

所在单位: 环境学院

电子邮箱: yangfl@dlut.edu.cn

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Conductive and hydrophilic polypyrrole modified membrane cathodes and fouling reduction in MBR

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论文类型: 期刊论文

发表时间: 2013-02-15

发表刊物: JOURNAL OF MEMBRANE SCIENCE

收录刊物: SCIE、EI

卷号: 429

页面范围: 252-258

ISSN号: 0376-7388

关键字: Membrane fouling; Membrane bioreactor; Conductive membrane; Polypyrrole; Electric field

摘要: For increasing separation efficiency and reducing energy consumption, study about membrane fouling reduction has ever been a hot topic. To prepare fouling-resistant, hydrophilic and conductive membrane, polyester filter cloth was modified with polypyrrole (PPy) in-situ formed by polymerization of pyrrole (concentration 3.868 g/L) and sodium dodecyl benzene sulfonate (SDBS). Increase in SDBS concentration (0.5, 1 or 2 g/L) during polymerization increased the membrane electric conductivity and hydrophilicity, and enhanced the permeate flux and anti-fouling properties of modified membrane. A voltage drop at 0.2 or 0.4 V/cm exhibited better fouling reduction than 0 V/cm. In the long-term filtration tests with the PPy (2 g/L SDBS) modified membrane, both the irreversible and the total resistances were decreased (5 times and 2 times, respectively) by applying 0.2 V/cm electric field, indicating the effect of applied electric field towards fouling reduction. The membrane cathode successfully prevented the pore clogging. (C) 2012 Elsevier B.Y. All rights reserved.

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