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个人信息Personal Information
教授
硕士生导师
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：应用化学. 精细化工. 分析化学
电子邮箱：zhanghua@dlut.edu.cn
PyHBr3/TBN/H2O as catalytic system for the oxidation of sulfides to sulfoxides with air as the oxidant
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论文类型：期刊论文
发表时间：2014-01-01
发表刊物：TETRAHEDRON LETTERS
收录刊物：SCIE、Scopus
卷号：55
期号：1
页面范围：56-58
ISSN号：0040-4039
关键字：Sulfides; Oxidation; Sulfoxides; Pyridinium bromide perbromide; tert-Butyl nitrite (TBN); Air
摘要：Pyridinium bromide perbromide (PyHBr3) and tert-butyl nitrite (TBN) catalytic system was used for the oxidation of sulfides with air as the oxidant. Under mild conditions (at room temperature), a series of sulfide substrates have been oxidized to their corresponding sulfoxides with high conversion rate. To the best of our knowledge, for the first time, the PyHBr3/TBN/H2O is reported as exceptional catalyst system for the oxidation discussed in this Letter. (C) 2013 Elsevier Ltd. All rights reserved.