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论文类型：期刊论文

发表时间：2017-12-01

发表刊物：ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH

收录刊物：SCIE、PubMed

卷号：24

期号：34

页面范围：26874-26880

ISSN号：0944-1344

关键字：Reduced graphene oxide materials; Nitrobenzene reduction; Shewanella oneidensis MR-1; Surface modification; Electrical conductivity; Electron shuttles

摘要：Reduced graphene oxide (rGO) can enhance the bioreduction of nitrobenzene by Shewanella oneidensis MR1. The effects of surface modification and coexisting soluble electron shuttles on rGO-enhanced bioreduction of nitrobenzene were investigated here. The results showed that rGO enhanced the secretion of extracellular polymeric substance and the bioreduction of nitrobenzene of several folds. No inhibition effect on nitrobenzene bioreduction was observed even when the concentration of rGO was as high as 200 mg/L. The surface modification of rGO might affect the electrical conductivity which was assumed as one of the main factors that contributed to the enhancement of nitrobenzene bioreduction by rGO materials. Moreover, the coexisting electron shuttles further enhanced the rGO-mediated nitrobenzene bioreduction. After the simultaneous addition of flavin mononucleotide (10 mu M) and rGO (50 mg/L), the reduction rate increased 7.8 times to 424.98 +/- 7.84 mg (nitrobenzene)/(g (dry cell).h), which was higher than those ever reported.