Bamberger Rearrangement of N-Arylhydroxylamine to p-Aminophenol in a CO2-H2O system
Release Time:2019-03-09 Hits:
Indexed by: Journal Article
Date of Publication: 2014-05-21
Journal: INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
Included Journals: Scopus、EI、SCIE
Volume: 53
Issue: 20
Page Number: 8372-8375
ISSN: 0888-5885
Abstract: The Bamberger rearrangement of N-aryllhydroxylamine was first realized in a CO2-H2O system. The yield of p-aminophenol was 80% when N-phenylhydroxylamine was heated at 100 degrees C for 1 h under 4 MPa CO2. The process fully avoids the need of inorganic strong acid and is environmentally benign.
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