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Indexed by:期刊论文

Date of Publication:2008-01-01

Journal:CHINESE CHEMICAL LETTERS

Included Journals:SCIE、ISTIC

Volume:19

Issue:1

Page Number:102-104

ISSN No.:1001-8417

Key Words:palladium; nanoparticle; selective hydrogenation; 1,5-cyclooctadiene; thermoregulated PEG biphase system

Abstract:Polyethylene glycol (PEG)-stabilized palladium nanoparticles were prepared and applied to the selective hydrogenation of 1,5-cyclooctadiene (1,5-COD) in thermoregulated PEG biphase system, which allows a reaction in a single-phase at a higher temperature followed by a phase split at a lower temperature. Under the optimized reaction conditions, the conversion of 1,5-COD and the selectivity of cyclooctene (COE) were 100 and 98%, respectively. The catalyst could be easily separated from the product by phase separation and reused for 6 times without evident loss in activity and selectivity. (c) 2007 Yan Hua Wang. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.