|
个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：有机化学
电子邮箱：jyjiang@dlut.edu.cn
扫描关注
Promoting effect of ethanol on the synthesis of N-(2-methylphenyl) hydroxylamine from o-nitrotoluene in Zn/H2O/CO2 system
点击次数：
论文类型：期刊论文
发表时间：2011-02-01
发表刊物：CHINESE CHEMICAL LETTERS
收录刊物：SCIE、ISTIC
卷号：22
期号：2
页面范围：221-224
ISSN号：1001-8417
关键字：o-Nitrotoluene; N-(2-Methylphenyl)hydroxylamine; Reduction; Zn; CO2/H2O
摘要：The promoting effect of ethanol on the synthesis of N-(2-methylphenyl)hydroxylamine from o-nitrotoluene in Zn/H2O/CO2 system was observed. By adding appropriate amount of ethanol, the selectivity of N-(2-methylphenyl)hydroxylamine increased from 71% to 90% when the reduction was carried out at 25 degrees C under normal pressure of CO2. (C) 2010 Published by Elsevier B.V. on behalf of Chinese Chemical Society.