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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：有机化学
电子邮箱：jyjiang@dlut.edu.cn
扫描关注
Environmentally benign and selective reduction of nitroarenes with Fe in pressurized CO2-H2O medium
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论文类型：期刊论文
发表时间：2008-01-01
发表刊物：GREEN CHEMISTRY
收录刊物：SCIE
卷号：10
期号：4
页面范围：439-441
ISSN号：1463-9262
摘要：A new method for reduction of nitroarenes employing metallic iron in pressurized CO2-H2O medium has been developed. p-Chloronitrobenzene can be reduced to the corresponding amine with a yield of 99% under the optimized conditions. The method is also applicable for the reduction of other substituted nitroarenes. After the reduction, the reaction mixture is self-neutralized on releasing of CO2. The method is environmentally benign, easily scaled-up and applicable for the preparation of substituted anilines.