论文名称：Synthesis and time-gated fluorometric application of a europium(III) complex with a borono-substituted terpyridine polyacid ligand
论文类型：期刊论文
发表刊物：TALANTA
收录刊物：SCIE、EI、PubMed
卷号：91
页面范围：116-121
ISSN号：0039-9140
关键字：Europium complex; Hydrogen peroxide; Luminescence probe; Suzuki cross-coupling reaction; Time-gated luminescence
摘要：A new europium(III) complex with a borono-substituted terpyridine polyacid ligand, (4'-borono-2,2':6',2 ''-terpyridine-6,6 ''-diyl) bis(methylenenitrilo) tetrakis(acetate)-Eu3+ (BTTA-Eu3+), has been designed and synthesized as a luminescence probe for hydrogen peroxide (H2O2). The complex is highly luminescent in aqueous buffers to display a typical Eu3+ emission pattern with a sharp emission peak at 610 nm and a long luminescence lifetime of 1.34 ms. Upon reaction with H2O2, the deboronation derivative of BTTA-Eu3+, (4'-hydroxy-2,2':6',2 ''-terpyridine-6,6 ''-diyl) bis(methylenenitrilo) tetrakis(acetate)-Eu3+ (HTTA-Eu3+), can be generated. It was found that the luminescence of BTTA-Eu3+ was pH-insensitive, whereas that of HTTA-Eu3+ was pH-dependent and could be remarkably weakened in neutral and basic buffers, which allowed BITA-Eu3+ to be a luminescence probe for the time-gated luminescence detection of H2O2 in neutral and basic buffers. The H2O2-BTTA-Eu3+ system was applied to monitor the kinetics of the palladium-catalyzed Suzuki cross-coupling reaction between BTTA-Eu3+ and bromobenzene, which suggested a useful strategy for the application of time-gated luminescence technique in catalysis reaction researches. (C) 2012 Elsevier B.V. All rights reserved.
发表时间：2012-03-15