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副教授

硕士生导师

性别:男

毕业院校:日本弘前大学

学位:博士

所在单位:化工学院

电子邮箱:youhx@dlut.edu.cn

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The conversion among reactions at Ni-based anodes in solid oxide fuel cells with low concentrations of dry methane

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论文类型:期刊论文

发表时间:2011-03-01

发表刊物:JOURNAL OF POWER SOURCES

收录刊物:Scopus、SCIE、EI

卷号:196

期号:5

页面范围:2779-2784

ISSN号:0378-7753

关键字:Solid oxide fuel cell; Anode; Methane; Reaction

摘要:Dry methane with different concentrations is directly fed to solid oxide fuel cells (SOFCs) with a Ni-yttria-stabilized zirconia (Ni-YSZ) anode and a Ni-scandia-stabilized zirconia (Ni-ScSZ) anode. The anode outlet gases are measured in situ by gas chromatography (GC) to study the reactions of dry methane at different current densities. The comparison between the measured open-circuit voltages (OCVs) and theoretical values, the quantitative analysis of components under different current densities and the activation energy analysis of elementary reactions of CH(4) are investigated to identify the types of reactions occurring to methane in SOFCs. It is found that reactions of partial oxidation, CH(4) + 2O(2-) -> CO + H(2)O + H(2) + 4e(-), CH(4) + 3O(2-) -> CO + 2H(2)O + 6e(-). and complete oxidation occur to CH(4) at the Ni-based anodes in sequence while the current density increasing. (C) 2010 Elsevier B.V. All rights reserved.