Release Time:2019-03-13  Hits:

Indexed by: Journal Article

Date of Publication: 2016-03-14

Journal: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Included Journals: PubMed、EI、SCIE

Volume: 55

Issue: 12

Page Number: 4030-4034

ISSN: 1433-7851

Key Words: hydrodesulfurization; nickel phosphides; selective hydrogenation; sulfur-containing layer

Abstract: Preparation of Ni2P by temperature-programmed reduction (TPR) of a phosphate precursor is challenging because the P-O bond is strong. An alternative approach to synthesizing Ni2P, by reduction of nickel hexathiodiphosphate (Ni2P2S6), is presented. Conversion of Ni2P2S6 into Ni2P occurs at 200-220 degrees C, a temperature much lower than that required by the conventional TPR method (typically 500 degrees C). A sulfur-containing layer with a thickness of about 4.7nm, composed of tiny crystallites, was observed at the surface of the obtained Ni2P catalyst (Ni2P-S). This is a direct observation of the sulfur-containing layer of Ni2P, or the so-called nickel phosphosulfide phase. Both the hydrodesulfurization activity and the selective hydrogenation performance of Ni2P-S were superior to that of the catalyst prepared by the TPR method, suggesting a positive role of sulfur on the surface of Ni2P-S. These features render Ni2P-S a legitimate alternative non-precious metal catalyst for hydrogenation reactions.