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Indexed by:期刊论文

Date of Publication:2012-06-14

Journal:JOURNAL OF MATERIALS CHEMISTRY

Included Journals:SCIE、EI、Scopus

Volume:22

Issue:22

Page Number:11121-11127

ISSN No.:0959-9428

Abstract:In the present study, molybdenum phosphide (MoP), nickel phosphide (Ni5P4), and carbon-supported Ni5P4 (Ni5P4/C) were proposed for use as counter electrode (CE) catalysts in dye-sensitized solar cells (DSCs) for the regeneration of both the conventional I-3(-)/I- redox couple and a new organic T-2/T- redox couple. For the I-3(-)/I- redox couple, the DSCs using MoP and Ni5P4 CE yielded a power conversion efficiency (PCE) of 4.92 and 5.71%, and the DSC using Ni5P4/C showed a high PCE of 7.54%, which was close to that of the DSC using Pt CE (7.76%). For the T-2/T- redox couple, Ni5P4/C performed much better than Pt and the DSC using Ni5P4/C CE showed a PCE of 4.75%, much higher than the photovoltaic performance of the DSC using Pt CE (3.38%).