The synthesis of metal phosphides: Reduction of oxide precursors in a hydrogen plasma
Release Time:2019-03-10 Hits:
Indexed by: Journal Article
Date of Publication: 2008-07-01
Journal: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Included Journals: Scopus、PubMed、EI、SCIE
Volume: 47
Issue: 32
Page Number: 6052-6054
ISSN: 1433-7851
Key Words: hydrogen; nickel; plasma chemistry; pnicticles; reduction
Abstract: (Equation Presented) A NiPpy phosphide synthesis: Nickel phosphides such as Ni2P and Ni3P are synthesized stoichiometrically from oxide precursors in a nonthermal hydrogen plasma at atmospheric pressure and low temperature in 60 min (see scheme). This energy- and time-efficient approach can also be applied to the synthesis of other metal phosphides such as GaP, InP, MoP, and WP. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.